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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Staudinger, Ulrike
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Topics
Publications (7/7 displayed)
- 2022Influence of CNT Length on Dispersion, Localization, and Electrical Percolation in a Styrene-Butadiene-Based Star Block Copolymercitations
- 2020Influence of Controlled Epoxidation of an Asymmetric Styrene/Butadiene Star Block Copolymer on Structural and Mechanical Properties
- 2020Influence of Controlled Epoxidation of an Asymmetric Styrene/Butadiene Star Block Copolymer on Structural and Mechanical Propertiescitations
- 2020Dispersion and Localization Behavior of Modified MWCNTs in Immiscible Polymer Blends of Polystyrene and Polybutadiene and in Corresponding Nanostructured Block Copolymerscitations
- 2019Nanofiller Dispersion, Morphology, Mechanical Behavior, and Electrical Properties of Nanostructured Styrene-Butadiene-Based Triblock Copolymer/CNT Compositescitations
- 2019Nanofiller dispersion, morphology, mechanical behavior, and electrical properties of nanostructured styrene-butadiene-based triblock copolymer/CNT composites
- 2014Dispersability of multiwalled carbon nanotubes in polycarbonate-chloroform solutionscitations
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article
Nanofiller Dispersion, Morphology, Mechanical Behavior, and Electrical Properties of Nanostructured Styrene-Butadiene-Based Triblock Copolymer/CNT Composites
Abstract
<jats:p>A nanostructured linear triblock copolymer based on styrene and butadiene with lamellar morphology is filled with multiwalled carbon nanotubes (MWCNTs) of up to 1 wt% by melt compounding. This study deals with the dispersability of the MWCNTs within the nanostructured matrix and its consequent impact on block copolymer (BCP) morphology, deformation behavior, and the electrical conductivity of composites. By adjusting the processing parameters during melt mixing, the dispersion of the MWCNTs within the BCP matrix are optimized. In this study, the morphology and glass transition temperatures (Tg) of the hard and soft phase are not significantly influenced by the incorporation of MWCNTs. However, processing-induced orientation effects of the BCP structure are reduced by the addition of MWCNT accompanied by a decrease in lamella size. The stress-strain behavior of the triblock copolymer/MWCNT composites indicate higher Young’s modulus and pronounced yield point while retaining high ductility (strain at break ~ 400%). At a MWCNT content of 1 wt%, the nanocomposites are electrically conductive, exhibiting a volume resistivity below 3 × 103 Ω·cm. Accordingly, the study offers approaches for the development of mechanically flexible functional materials while maintaining a remarkable structural property profile.</jats:p>