| People | Locations | Statistics |
|---|---|---|
| Naji, M. |
| |
| Motta, Antonella |
| |
| Aletan, Dirar |
| |
| Mohamed, Tarek |
| |
| Ertürk, Emre |
| |
| Taccardi, Nicola |
| |
| Kononenko, Denys |
| |
| Petrov, R. H. | Madrid |
|
| Alshaaer, Mazen | Brussels |
|
| Bih, L. |
| |
| Casati, R. |
| |
| Muller, Hermance |
| |
| Kočí, Jan | Prague |
|
| Šuljagić, Marija |
| |
| Kalteremidou, Kalliopi-Artemi | Brussels |
|
| Azam, Siraj |
| |
| Ospanova, Alyiya |
| |
| Blanpain, Bart |
| |
| Ali, M. A. |
| |
| Popa, V. |
| |
| Rančić, M. |
| |
| Ollier, Nadège |
| |
| Azevedo, Nuno Monteiro |
| |
| Landes, Michael |
| |
| Rignanese, Gian-Marco |
|
Papadopoulos, Lazaros
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (11/11 displayed)
- 2024Influence of reactive diluent composition on properties and bio-based content of itaconic acid-based additive manufacturing materialscitations
- 2024Itaconic acid-based 3D printed nanocomposites: An in-depth study on the effect of nanoinclusions on the physicochemical properties and the printability of formulations based on polyester itaconatescitations
- 2024Melting Behavior of Compression Molded Poly(ester amide) from 2,5-Furandicarboxylic Acid
- 2023Bio-based additive manufacturing materials: An in-depth structure-property relationship study of UV-curing polyesters from itaconic acidcitations
- 2021Comparative study of crystallization, semicrystalline morphology, and molecular mobility in nanocomposites based on polylactide and various inclusions at low filler loadingscitations
- 2021Synthesis and Characterization of Unsaturated Succinic Acid Biobased Polyester Resinscitations
- 2021Properties of poly(lactic acid)/montmorillonite/carbon nanotubes nanocomposites: determination of percolation thresholdcitations
- 2021Bottom-up development of nanoimprinted PLLA composite films with enhanced antibacterial properties for smart packaging applicationscitations
- 2021Bottom-up development of nanoimprinted PLLA composite films with enhanced antibacterial properties for smart packaging applicationscitations
- 2019Thermal Decomposition Kinetics and Mechanism of In-Situ Prepared Bio-based Poly(propylene 2,5-furan dicarboxylate)/Graphene Nanocompositescitations
- 2018Synthesis and characterization of in-situ-prepared nanocomposites based on poly(propylene 2,5-furan dicarboxylate) and aluminosilicate clayscitations
Places of action
| Organizations | Location | People |
|---|
article
Synthesis and characterization of in-situ-prepared nanocomposites based on poly(propylene 2,5-furan dicarboxylate) and aluminosilicate clays
Abstract
Poly(propylene 2,5-furan dicarboxylate) (PPF), or poly(trimethylene 2,5-furan dicarboxylate) (PTF), is a biobased alipharomatic polyester that is expected to replace its fossil-based terephthalate (PPT) and naphthate (PPN) homologues. PPF possesses exceptional gas barrier properties, but its slow crystallization rate might affect its success in specific applications in the future. Therefore, a series of PPF based nanocomposites with the nanoclays Cloisite®-Na (MMT), Cloisite®-20A (MMT 20A), and halloysite nanotubes (HNT)were synthesized via the in situ transterification and polycondensation method. The effect of the nanoclays on the structure, thermal, and crystallization properties of PPF was studied with several methods including infrared spectroscopy (IR), Nuclear Resonance Spectroscopy ( 1 H-NMR), Wide Angle X-ray Diffraction (WAXD), Thermogravimetric Analysis (TGA), and Differential Scanning Calorimetry (DSC). The insertion of the nanofillers in the polymer matrix altered the crystallization rates, and TGA results showed good thermal stability, since no significant mass loss occurred up to 300 °C. Finally, the degradation mechanism was studied in depth with Pyrolysis-Gas Chromatography/Mass Spectroscopy, and it was found that β-scission is the dominant degradation mechanism.