| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Tirri, Teija
Åbo Akademi University
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (10/10 displayed)
- 2023Dry Reforming of Methane over Ni-Fe-Al Catalysts Prepared by Solution Combustion Synthesiscitations
- 2021On Laccase-Catalyzed Polymerization of Biorefinery Lignin Fractions and Alignment of Lignin Nanoparticles on the Nanocellulose SurfaceviaOne-Pot Water-Phase Synthesiscitations
- 2021On Laccase-Catalyzed Polymerization of Biorefinery Lignin Fractions and Alignment of Lignin Nanoparticles on the Nanocellulose Surface via One-Pot Water-Phase Synthesiscitations
- 2021Sulfenamides as Standalone Flame Retardants for Polystyrenecitations
- 2020Tailored thermosetting wood adhesive based on well-defined hardwood lignin fractionscitations
- 2018The Synthesis of Low-Viscosity Organotin-Free Moisture-Curable Silane-Terminated Poly(Urethane-Urea)scitations
- 2017Investigation on the Influence of Chain Extenders on the Performance of One-Component Moisture-Curable Polyurethane Adhesivescitations
- 2016Structure–Property Studies on a New Family of Halogen Free Flame Retardants Based on Sulfenamide and Related Structurescitations
- 2015The effect of core-shell particle morphology on adhesive properties of poly(styrene-co-butyl acrylate)citations
- 2013Flame retardant polyurethane nanocomposite: Study of clay dispersion and its synergistic effect with dolomitecitations
Places of action
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article
The Synthesis of Low-Viscosity Organotin-Free Moisture-Curable Silane-Terminated Poly(Urethane-Urea)s
Abstract
This work explores the possibility of synthesizing moisture-curable silane-terminated poly(urethane-urea)s (SPURs) of low viscosity. First, NCO-terminated urethane prepolymers were prepared, followed by silane end-capping. The impact of polyol molecular weight and the ratio of isocyanate to polyol (NCO/OH) on viscosity and the properties of SPUR were examined. As alternatives to the organotin catalysts traditionally used for the polyurethane synthesis and curing processes, bismuth carboxylate catalysts were evaluated. In addition, the effect of organofunctional groups in the aminosilane structure (R1–NH–R2–Si(OR3)3), i.e., R1 (alkyl, aryl or trimethoxysilyl-propyl), the spacer R2 (α or γ) and alkyl group R3 (methyl or ethyl), was examined. The chemical and physical structures of the SPUR were investigated by nuclear magnetic resonance spectroscopy (NMR), Fourier transform infrared spectroscopy (FT-IR) and the mechanical properties were evaluated by tensile tests. The results reveal that silane-terminated, moisture-curable polyurethanes can be successfully synthesized and cured with bismuth carboxylate catalysts. SPUR exhibiting low viscosity, with adequate tensile strength and elongation can be prepared using environmentally benign bismuth carboxylate catalyst having a high metal content of 19%–21%, by utilizing secondary aminosilane end-cappers and an optimal combination of the polyol molecular weight and NCO/OH ratio.