| People | Locations | Statistics |
|---|---|---|
| Naji, M. |
| |
| Motta, Antonella |
| |
| Aletan, Dirar |
| |
| Mohamed, Tarek |
| |
| Ertürk, Emre |
| |
| Taccardi, Nicola |
| |
| Kononenko, Denys |
| |
| Petrov, R. H. | Madrid |
|
| Alshaaer, Mazen | Brussels |
|
| Bih, L. |
| |
| Casati, R. |
| |
| Muller, Hermance |
| |
| Kočí, Jan | Prague |
|
| Šuljagić, Marija |
| |
| Kalteremidou, Kalliopi-Artemi | Brussels |
|
| Azam, Siraj |
| |
| Ospanova, Alyiya |
| |
| Blanpain, Bart |
| |
| Ali, M. A. |
| |
| Popa, V. |
| |
| Rančić, M. |
| |
| Ollier, Nadège |
| |
| Azevedo, Nuno Monteiro |
| |
| Landes, Michael |
| |
| Rignanese, Gian-Marco |
|
Dudziec, Beata
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (14/14 displayed)
- 2024Preparation of T8 and double-decker silsesquioxane-based Janus-type molecules: molecular modeling and DFT insights
- 2024Crystallization behavior and thermal properties of octa-phenyl-substituted silsesquioxane-modified polylactide (PLA)citations
- 2023Metallodendrimers Unveiled: Investigating the Formation and Features of Double-Decker Silsesquioxane-Based Silylferrocene Dendrimerscitations
- 2022Slick Synthetic Approach to Various Fluoroalkyl Silsesquioxanes—Assessment of their Dielectric Propertiescitations
- 2019Synthetic routes to silsesquioxane-based systems as photoactive materials and their precursorscitations
- 2018Multi-alkenylsilsesquioxanes as comonomers and active species modifiers of metallocene catalyst in copolymerization with ethylenecitations
- 2018Interfacial interactions in PTT–PTMO/polyhedral oligomeric silsesquioxane (POSS) nanocomposites and their impact on mechanical, thermal, and dielectric propertiescitations
- 2017Copolymers of ethylene with monoalkenyl- and monoalkenyl(siloxy)silsesquioxane (POSS) comonomers – Synthesis and characterizationcitations
- 2017Evaluation of thermomechanical properties of epoxy–basalt fibre composites modified with zeolite and silsesquioxanecitations
- 2016Morphology, mechanical properties and processability of poly(ethylene terephthalate) modified by polyhedral oligomeric silsesquioxanes
- 2015Morphology and phase separation in PTT-block-PTMO nanocomposites containing POSS particlescitations
- 2014Influence of a sorbitol-based nucleating agent modified with silsesquioxanes on the non-isothermal crystallization of isotactic polypropylenecitations
- 2014Thermal Stability and Flammability of Polypropylene-Silsesquioxane Nanocompositescitations
- 2013Processing properties of thermoplastic polymers modified by polyhedral oligomeric silsesquioxanes (POSS)citations
Places of action
| Organizations | Location | People |
|---|
article
Multi-alkenylsilsesquioxanes as comonomers and active species modifiers of metallocene catalyst in copolymerization with ethylene
Abstract
The copolymers of ethylene (E) with open-caged iso-butyl-substituted tri-alkenyl-silsesquioxanes (POSS-6-3 and POSS-10-3) and phenyl-substituted tetra-alkenyl-silsesquioxane (POSS-10-4) were synthesized by copolymerization over the ansa-metallocene catalyst. The influence of the kind of silsesquioxane and of the copolymerization conditions on the reaction performance and on the properties of the copolymers was studied. In the case of copolymerization of E/POSS-6-3, the positive comonomer effect was observed, which was associated with the influence of POSS-6-3 on transformation of the bimetallic ion pair to the active catalytic species. Functionality of silsesquioxanes and polymerization parameters affected the polyhedral oligomeric silsesquioxanes (POSS) contents in the copolymers which varied in the range of 1.33-7.43 wt %. Tri-alkenyl-silsesquioxanes were incorporated into the polymer chain as pendant groups while the tetra-alkenyl-silsesquioxane derivative could act as a cross-linking agent which was proved by the changes in the contents of unsaturated end groups, by the glass transition temperature values, and by the gel contents (up to 81.3% for E/POSS-10-4). Incorporation of multi-alkenyl-POSS into the polymer chain affected also the melting and crystallization behaviors.</p>