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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Das, Amit
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (18/18 displayed)
- 2024Unlocking the Potential of Lignin: Towards a Sustainable Solution for Tire Rubber Compound Reinforcementcitations
- 2022Electrically conductive and piezoresistive polymer nanocomposites using multiwalled carbon nanotubes in a flexible copolyester: Spectroscopic, morphological, mechanical and electrical properties
- 2022Ferric Ions Crosslinked Epoxidized Natural Rubber Filled with Carbon Nanotubes and Conductive Carbon Black Hybrid Fillers
- 2021Treasuring waste lignin as superior reinforcing filler in high cis-polybutadiene rubbercitations
- 2020Friction, abrasion and crack growth behavior of in-situ and ex-situ silica filled rubber compositescitations
- 2020Verfahren zur Herstellung von Lignin-PAN-basierten Polymercompounds und Lignin-PAN-basierte Polymercompounds
- 2019Influence of Zn concentration on interfacial intermetallics during liquid and solid state reaction of hypo and hypereutectic Sn-Zn solder alloyscitations
- 2019The Taste of Waste: The Edge of Eggshell Over Calcium Carbonate in Acrylonitrile Butadiene Rubber
- 2019Devulcanization of Waste Rubber and Generation of Active Sites for Silica Reinforcement
- 2018Improved electromechanical response in acrylic rubber by different carbon-based fillerscitations
- 2018Temperature scanning stress relaxation of an autonomous self-healing elastomer containing non-covalent reversible network junctionscitations
- 2018Further enhancement of mechanical properties of conducting rubber composites based on multiwalled carbon nanotubes and Nitrile Rubber by solvent treatmentcitations
- 2017Strong Strain Sensing Performance of Natural Rubber Nanocompositescitations
- 2017Vegetable fillers for electric stimuli responsive elastomerscitations
- 2017Temperature-Dependent Reinforcement of Hydrophilic Rubber Using Ice Crystals
- 2016Improvement of actuation performance of dielectric elastomers by barium titanate and carbon black fillerscitations
- 2016Evaluation of mechanical and dynamic mechanical properties of multiwalled carbon nanotube-based ethylene–propylene copolymer composites mixed by masterbatch dilutioncitations
- 2015Rubber composites based on silane-treated stöber silica and nitrile rubber: Interaction of treated silica with rubber matrixcitations
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article
Temperature scanning stress relaxation of an autonomous self-healing elastomer containing non-covalent reversible network junctions
Abstract
In this work, we report about the mechanical relaxation characteristics of an intrinsically self-healable imidazole modified commercial rubber. This kind of self-healing rubber was prepared by melt mixing of 1-butyl imidazole with bromo-butyl rubber (bromine modified isoprene-isobutylene copolymer, BIIR). By this melt mixing process, the reactive allylic bromine of bromo-butyl rubber was converted into imidazole bromide salt. The resulting development of an ionic character to the polymer backbone leads to an ionic association of the groups which ultimately results to the formation of a network structure of the rubber chains. The modified BIIR thus behaves like a robust crosslinked rubber and shows unusual self-healing properties. The non-covalent reversible network has been studied in detail with respect to stress relaxation experiments, scanning electron microscopic and X-ray scattering. ; publishedVersion