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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Talochka, Yauheni
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Topics
Publications (3/3 displayed)
- 2024Transient processes in inorganic multicomponent crystalline scintillators and semiconductors / ; Kinetiniai procesai neorganiniuose daugiakomponenčiuose kristaliniuose scintiliatoriuose ir puslaidininkiuose.
- 2023On the Quenching Mechanism of Ce, Tb Luminescence and Scintillation in Compositionally Disordered $(Gd,Y,Yb)_3Al_2Ga_3O_{12}$ Garnet Ceramicscitations
- 2023On the Quenching Mechanism of Ce, Tb Luminescence and Scintillation in Compositionally Disordered (Gd, Y, Yb)3Al2Ga3O12 Garnet Ceramicscitations
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article
On the Quenching Mechanism of Ce, Tb Luminescence and Scintillation in Compositionally Disordered (Gd, Y, Yb)3Al2Ga3O12 Garnet Ceramics
Abstract
<jats:p>Two series of (Gd, Y, Yb)3Al2Ga3O12 quintuple compounds with a garnet structure and solely doped with Ce and Tb were prepared in the form of ceramics by sintering in oxygen at 1600 °C for two hours and studied for the interaction of activator ions with ytterbium ions entering the matrix. It was shown that the photoluminescence and scintillation of Ce3+ ions are completely suppressed, predominantly by tunneling ionization through the charge transfer state (CTS) of the Ce4+-Yb2+ ions. The photoluminescence of Tb3+ ions is quenched in the presence of ytterbium, but not completely due to the poor resonance conditions of Tb3+ intraconfiguration transitions and the CTS of the single Yb3+ and the CTS of Ce4+-Yb2+ ions. The scintillation in the visible range of both Ce3+- and Tb3+-doped samples is intensely quenched as well, which indicates strong competition from Yb3+ ions to activators in interaction with the Gd substrate.</jats:p>