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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Löffler, Tobias
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (16/16 displayed)
- 2024Self-formation of compositionally complex surface oxides on high entropy alloys: a route to sustainable catalysts
- 2022Zooming‐in - visualization of active site heterogeneity in high entropy alloy electrocatalysts using scanning electrochemical cell microscopycitations
- 2022Unravelling composition-activity-stability trends in high entropy alloy electrocatalysts by using a data‐guided combinatorial synthesis strategy and computational modelingcitations
- 2021What makes high‐entropy alloys exceptional electrocatalysts?citations
- 2021Bayesian optimization of high‐entropy alloy compositions for electrocatalytic oxygen reductioncitations
- 2021Comparing the activity of complex solid solution electrocatalysts using inflection points of voltammetric activity curves as activity descriptorscitations
- 2021Was macht Hochentropie‐Legierungen zu außergewöhnlichen Elektrokatalysateuren?citations
- 2020Complex‐solid‐solution electrocatalyst discovery by computational prediction and high‐throughput experimentationcitations
- 2020Sputter deposition of highly active complex solid solution electrocatalysts into an ionic liquid librarycitations
- 2020Design of complex solid solution electrocatalysts by correlating configuration, adsorption energy distribution patterns and activity curvescitations
- 2020Design von komplexen Mischkristall‐Elektrokatalysatoren auf Basis der Korrelation von Konfiguration, Verteilungsmustern der Adsorptionsenergie und Aktivitätskurvencitations
- 2019Toward a paradigm shift in electrocatalysis using complex solid solution nanoparticlescitations
- 2018Discovery of a multinary noble metal-free oxygen reduction catalystcitations
- 2018Controlling the Amorphous and Crystalline State of Multinary Alloy Nanoparticles in An Ionic Liquidcitations
- 2016Fourfold action of surfactants with superacid head groups: polyoxometalate–silicone nanocomposites as promising candidates for proton-conducting materialscitations
- 2016Fourfold action of surfactants with superacid head groups : polyoxometalate-silicone nanocomposites as promising candidates for proton-conducting materialscitations
Places of action
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article
Controlling the Amorphous and Crystalline State of Multinary Alloy Nanoparticles in An Ionic Liquid
Abstract
<jats:p>Controlling the amorphous or crystalline state of multinary Cr-Mn-Fe-Co-Ni alloy nanoparticles with sizes in the range between ~1.7 nm and ~4.8 nm is achieved using three processing routes. Direct current sputtering from an alloy target in the ionic liquid 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide leads to amorphous nanoparticles as observed by high-resolution transmission electron microscopy. Crystalline nanoparticles can be achieved in situ in a transmission electron microscope by exposure to an electron beam, ex situ by heating in vacuum, or directly during synthesis by using a high-power impulse magnetron sputtering process. Growth of the nanoparticles with respect to the amorphous particles was observed. Furthermore, the crystal structure can be manipulated by the processing conditions. For example, a body-centered cubic structure is formed during in situ electron beam crystallization while longer ex situ annealing induces a face-centered cubic structure.</jats:p>