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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Avgeropoulos, Apostolos
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (17/17 displayed)
- 2024Microwave-Assisted Extraction of Cellulose from Aloe Vera Plant Residue and Preparation of Cellulose Nanocrystal–Poly(vinyl alcohol) Hydrogelscitations
- 2023Thermal and Bulk Properties of Triblock Terpolymers and Modified Derivatives towards Novel Polymer Brushescitations
- 2023Synthesis and Structural Insight into Poly(dimethylsiloxane)-b-Poly(2-vinylpyridine) Copolymers
- 2022Microwave Synthesis, Characterization and Perspectives of Wood Pencil-Derived Carboncitations
- 2021Functionalization of single-walled carbon nanotubes with end-capped polystyrene via a single-step diels–alder cycloadditioncitations
- 2021Structure/Properties Relationship of Anionically Synthesized Diblock Copolymers “Grafted to” Chemically Modified Graphenecitations
- 2021Synthesis, Characterization and Structure Properties of Biobased Hybrid Copolymers Consisting of Polydiene and Polypeptide Segmentscitations
- 2021Synthesis, Characterization and Structure Properties of Biobased Hybrid Copolymers Consisting of Polydiene and Polypeptide Segmentscitations
- 2020Dendrons and Dendritic Terpolymers: Synthesis, Characterization and Self-Assembly Comparisoncitations
- 2019Examination of well ordered nanonetwork materials by real- and reciprocal-space imagingcitations
- 2018Metal (Ag/Ti)-Containing Hydrogenated Amorphous Carbon Nanocomposite Films with Enhanced Nanoscratch Resistance: Hybrid PECVD/PVD System and Microstructural Characteristicscitations
- 2017Indacenodithienothiophene-Based Ternary Organic Solar Cellscitations
- 2017Self-assembly of Polystyrene- b -poly(2-vinylpyridine)- b -poly(ethylene oxide) Triblock Terpolymerscitations
- 2016Nanocomposites based on nanostructured PI-b-PMMA copolymer and selectively placed PMMA-modified magnetic nanoparticles: Morphological and magnetic characterizationcitations
- 2015Amino-functionalized multiwalled carbon nanotubes lead to successful ring-opening polymerization of poLY(ε-caprolactone)citations
- 2015Amino-functionalized multiwalled carbon nanotubes lead to successful ring-opening polymerization of poLY(ε-caprolactone):Enhanced interfacial bonding and optimized mechanical propertiescitations
- 2012Nanohybrids based on polymeric ionic liquid prepared from functionalized MWCNTs by modification of anionically synthesized poly(4-vinylpyridine)citations
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article
Metal (Ag/Ti)-Containing Hydrogenated Amorphous Carbon Nanocomposite Films with Enhanced Nanoscratch Resistance: Hybrid PECVD/PVD System and Microstructural Characteristics
Abstract
<jats:p>This study aimed to develop hydrogenated amorphous carbon thin films with embedded metallic nanoparticles (a–C:H:Me) of controlled size and concentration. Towards this end, a novel hybrid deposition system is presented that uses a combination of Plasma Enhanced Chemical Vapor Deposition (PECVD) and Physical Vapor Deposition (PVD) technologies. The a–C:H matrix was deposited through the acceleration of carbon ions generated through a radio-frequency (RF) plasma source by cracking methane, whereas metallic nanoparticles were generated and deposited using terminated gas condensation (TGC) technology. The resulting material was a hydrogenated amorphous carbon film with controlled physical properties and evenly dispersed metallic nanoparticles (here Ag or Ti). The physical, chemical, morphological and mechanical characteristics of the films were investigated through X-ray reflectivity (XRR), Raman spectroscopy, Scanning Electron Microscopy (SEM), Atomic Force Microscopy (AFM), Transmission Electron Microscopy (TEM) and nanoscratch testing. The resulting amorphous carbon metal nanocomposite films (a–C:H:Ag and a–C:H:Ti) exhibited enhanced nanoscratch resistance (up to +50%) and low values of friction coefficient (<0.05), properties desirable for protective coatings and/or solid lubricant applications. The ability to form nanocomposite structures with tunable coating performance by potentially controlling the carbon bonding, hydrogen content, and the type/size/percent of metallic nanoparticles opens new avenues for a broad range of applications in which mechanical, physical, biological and/or combinatorial properties are required.</jats:p>