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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Kónya, Zoltán
University of Szeged
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (11/11 displayed)
- 2024Influence of rapid heat treatment on the photocatalytic activity and stability of calcium titanates against a broad range of pollutantscitations
- 2024Ball-Milling Enhanced UV Protection Performance of Ca2Fe-Sulisobenzone Layered Double Hydroxide Organic Claycitations
- 2024Enhancing the dipole ring of hexagonal boron nitride nanomesh by surface alloyingcitations
- 2023Differently prepared PbO2/graphitic carbon nitride composites for efficient electrochemical removal of Reactive Black 5 dyecitations
- 2023Highly porous polymer beads coated with nanometer-thick metal oxide films for photocatalytic oxidation of bisphenol Acitations
- 2023Noble metal nanoparticles and nanodiamond modified strontium titanate photocatalysts for room temperature CO production from direct hydrogenation of CO2citations
- 2022Investigation into the effect of ZnO nanorod coating on the thermal-mechanical and dielectric properties of ITO coated PETcitations
- 2020Fast optical method for characterizing plasmonic nanoparticle adhesion on functionalized surfacescitations
- 2020Mechanochemistry for catalysis: preparation of perovskite structural materials and mixtures of metal oxides
- 2020Cu–Fe Incorporated Graphene-Oxide Nanocomposite as Highly Efficient Catalyst in the Degradation of Dichlorodiphenyltrichloroethane (DDT) from Aqueous Solution
- 2016Synthesis of high-quality, well-characterized CaAlFe-layered triple hydroxide with the combination of dry-milling and ultrasonic irradiation in aqueous solution at elevated temperaturecitations
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article
Ball-Milling Enhanced UV Protection Performance of Ca2Fe-Sulisobenzone Layered Double Hydroxide Organic Clay
Abstract
Using a co-precipitation technique, the anionic form of sulisobenzone (benzophenone-4) sunscreen ingredient was incorporated into the interlayer space of CaFe-hydrocalumite for the first time. Using detailed post-synthetic millings of the photoprotective nanocomposite obtained, we aimed to study the mechanochemical effects on complex, hybridized layered double hydroxides (LDHs). Various physicochemical properties of the ground and the intact LDHs were compared by powder X-ray diffractometry, N2 adsorption-desorption, UV–Vis diffuse reflectance, infrared and Raman spectroscopy, scanning electron microscopy and thermogravimetric measurements. The data showed significant structural and morphological deformations, surface and textural changes and multifarious thermal behavior. The most interesting development was the change in the optical properties of organic LDHs; the milling significantly improved the UV light blocking ability, especially around 320 nm. Spectroscopic results verified that this could be explained by a modification in interaction between the LDH layers and the sulisobenzone anions, through modulated π–π conjugation and light absorption of benzene rings. In addition to the vibrating mill often used in the laboratory, the photoprotection reinforcement can also be induced by the drum mill grinding system commonly applied in industry.