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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Boukos, Nikos
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (6/6 displayed)
- 2023In Tandem Control of La-Doping and CuO-Heterojunction on SrTiO3 Perovskite by Double-Nozzle Flame Spray Pyrolysis: Selective H2 vs. CH4 Photocatalytic Production from H2O/CH3OHcitations
- 2023Covalently Modified Kevlar Fabric Incorporating Graphene Oxide with Enhanced Antibacterial Properties and Preserved Strengthcitations
- 2023Kevlar®, Nomex®, and VAR Modification by Small Organic Molecules Anchoring: Transfusing Antibacterial Properties and Improving Water Repellencycitations
- 2019Effects of Precursor Concentration in Solvent and Nanomaterials Room Temperature Aging on the Growth Morphology and Surface Characteristics of Ni–NiO Nanocatalysts Produced by Dendrites Combustion during SCScitations
- 2019Effects of Precursor Concentration in Solvent and Nanomaterials Room Temperature Aging on the Growth Morphology and Surface Characteristics of Ni–NiO Nanocatalysts Produced by Dendrites Combustion during SCScitations
- 2014Atomic-layer-deposited aluminum and zirconium oxides for surface passivation of TiO 2 in high-efficiency organic photovoltaicscitations
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article
In Tandem Control of La-Doping and CuO-Heterojunction on SrTiO3 Perovskite by Double-Nozzle Flame Spray Pyrolysis: Selective H2 vs. CH4 Photocatalytic Production from H2O/CH3OH
Abstract
<jats:p>ABO3 perovskites offer versatile photoactive nano-templates that can be optimized towards specific technologies, either by means of doping or via heterojunction engineering. SrTiO3 is a well-studied perovskite photocatalyst, with a highly reducing conduction-band edge. Herein we present a Double-Nozzle Flame Spray Pyrolysis (DN-FSP) technology for the synthesis of high crystallinity SrTiO3 nanoparticles with controlled La-doping in tandem with SrTiO3/CuO-heterojunction formation. So-produced La:SrTiO3/CuO nanocatalysts were optimized for photocatalysis of H2O/CH3OH mixtures by varying the La-doping level in the range from 0.25 to 0.9%. We find that, in absence of CuO, the 0.9La:SrTiO3 material achieved maximal efficient photocatalytic H2 production, i.e., 12 mmol g−1 h−1. Introduction of CuO on La:SrTiO3 enhanced selective production of methane CH4. The optimized 0.25La:SrTiO3/0.5%CuO catalyst achieved photocatalytic CH4 production of 1.5 mmol g−1 h−1. Based on XRD, XRF, XPS, BET, and UV-Vis/DRS data, we discuss the photophysical basis of these trends and attribute them to the effect of La atoms in the SrTiO3 lattice regarding the H2-production, plus the effect of interfacial CuO on the promotion of CH4 production. Technology-wise this work is among the first to exemplify the potential of DN-FSP for scalable production of complex nanomaterials such as La:SrTiO3/CuO with a diligent control of doping and heterojunction in a single-step synthesis.</jats:p>