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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Coppel, Yannick
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (15/15 displayed)
- 2024Towards chitosan-amorphous calcium phosphate nanocomposite: Co-precipitation induced by spray dryingcitations
- 2024Spray-dried ternary bioactive glass microspheres: Direct and indirect structural effects of copper-doping on acellular degradation behaviorcitations
- 2024Synthesis of TiO2/SBA-15 Nanocomposites by Hydrolysis of Organometallic Ti Precursors for Photocatalytic NO Abatement
- 2023Effect of Oxygen Poisoning on the Bidirectional Hydrogen Electrocatalysis in TaS2 Nanosheetscitations
- 2023Effect of Oxygen Poisoning on the Bidirectional Hydrogen Electrocatalysis in TaS 2 Nanosheetscitations
- 2022Nano-Structuration of WO3 Nanoleaves by Localized Hydrolysis of an Organometallic Zn Precursor: Application to Photocatalytic NO2 Abatementcitations
- 2022Nano-Structuration of WO3 Nanoleaves by Localized Hydrolysis of an Organometallic Zn Precursor: Application to Photocatalytic NO2 Abatementcitations
- 2022Bioactive glass nanoparticles decorated with catechol-functionalized polyesters: towards macroporous nanocomposite scaffolds
- 2020Nanoscale Metal Phosphide Phase Segregation to Bi/P Core/Shell Structure. Reactivity as a Source of Elemental Phosphoruscitations
- 2020Nanoscale Metal Phosphide Phase Segregation to Bi/P Core/Shell Structure. Reactivity as a Source of Elemental Phosphoruscitations
- 2019Urea-assisted cooperative assembly of phosphorus dendrimer–zinc oxide hybrid nanostructurescitations
- 2018A novel method for the metallization of 3D silicon induced by metastable copper nanoparticlescitations
- 2017Stabilization of Colloidal Ti, Zr, and Hf Oxide Nanocrystals by Protonated Tri- n -octylphosphine Oxide (TOPO) and Its Decomposition Products
- 2008Tailored Control and Optimisation of the Number of Phosphonic Acid Termini on Phosphorus-Containing Dendrimers for the Ex-Vivo Activation of Human Monocytescitations
- 2008Organotin chemistry for the preparation of fullerene-rich nanostructurescitations
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article
Nano-Structuration of WO3 Nanoleaves by Localized Hydrolysis of an Organometallic Zn Precursor: Application to Photocatalytic NO2 Abatement
Abstract
<jats:p>WO3 is a known photocatalytic metal oxide frequently studied for its depollution properties. However, it suffers from a high recombination rate of the photogenerated electron/holes pair that is detrimental to its performance. In this paper, we present a new chemical method to decorate WO3 nanoleaves (NLs) with a complementary metal oxide (ZnWO4) in order to improve the photocatalytic performance of the composite material for the abatement of 400 ppb NO2 under mild UV exposure. Our strategy was to synthesize WO3·2H2O nanoleaves, then, to expose them, in water-free organic solution, to an organometallic precursor of Zn(Cy)2. A structural water molecule from WO3·2H2O spontaneously decomposes Zn(Cy)2 and induces the formation of the ZnO@WO3·H2O nanocomposite. The material was characterized by electronic microscopy (SEM, TEM), TGA, XRD, Raman and solid NMR spectroscopies. A simple thermal treatment under air at 500 °C affords the ZnWO4@WO3 nanocomposite. The resulting material, additionally decorated with 1% wt. Au, presents a remarkable increase (+166%) in the photocatalytic abatement of NO2 under UV compared to the pristine WO3 NLs. This synthesis method paves the way to the versatile preparation of a wide range of MOx@WO3 nanocomposites (MOx = metal oxide).</jats:p>