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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Fau, Pierre
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (27/27 displayed)
- 2024Synthesis of TiO2/SBA-15 Nanocomposites by Hydrolysis of Organometallic Ti Precursors for Photocatalytic NO Abatement
- 2023Gas Sensing Properties of CuWO4@WO3 n-n Heterojunction Prepared by Direct Hydrolysis of Mesitylcopper (I) on WO3·2H2O Nanoleavescitations
- 2023Gas Sensing Properties of CuWO4@WO3 n-n Heterojunction Prepared by Direct Hydrolysis of Mesitylcopper (I) on WO3·2H2O Nanoleavescitations
- 2022Grafting Copper Atoms and Nanoparticles on Double-Walled Carbon Nanotubes: Application to Catalytic Synthesis of Propargylaminecitations
- 2022Nano-Structuration of WO3 Nanoleaves by Localized Hydrolysis of an Organometallic Zn Precursor: Application to Photocatalytic NO2 Abatementcitations
- 2022Nano-Structuration of WO3 Nanoleaves by Localized Hydrolysis of an Organometallic Zn Precursor: Application to Photocatalytic NO2 Abatementcitations
- 2022Grafting Copper Atoms and Nanoparticles on Double-Walled Carbon Nanotubes ; Grafting Copper Atoms and Nanoparticles on Double-Walled Carbon Nanotubes: Application to Catalytic Synthesis of Propargylaminecitations
- 2022Towards Selective and Sensitive Detection of Carbon Monoxide with CuO/ZnO Heterojunction NanocompositePrepared by an Organometallic Approach
- 2022Towards selective and sensitive detection of carbon monoxide with CuO/ZnO heterojunction nanocomposite prepared by an organometallic approach
- 2019Removable Composite Electrode Made of Silver Nanoparticles on Pyrolyzed Photoresist Film for the Electroreduction of 4-Nitrophenolcitations
- 2018Air-stable anisotropic monocrystalline nickel nanowires characterized using electron holographycitations
- 2018Impregnation of High-Magnetization FeCo Nanoparticles in Mesoporous Silicon: An Experimental Approachcitations
- 2018A novel method for the metallization of 3D silicon induced by metastable copper nanoparticlescitations
- 2017Synthesis and electrical characterization of monocrystalline nickel nanorods and Ni-CNT composites
- 2017Au/MOx (M = Zn, Ti) nanocomposites as highly efficient catalytic filters for chemical gas sensing at room temperature and in humid atmospherecitations
- 2017Organometallic Synthesis of CuO Nanoparticles: Application in Low‐Temperature CO Detectioncitations
- 2016SnO2 "Russian Doll" octahedra prepared by metalorganic synthesis: A new structure for sub-ppm CO detectioncitations
- 2016SnO<sub>2</sub> “Russian Doll” Octahedra Prepared by Metalorganic Synthesis: A New Structure for Sub‐ppm CO Detectioncitations
- 2016Sub-ppm CO Gas Sensor
- 2015Self-Assembled Hollow SnO2 Octahedra for sub-ppm Gas Detection Sensors
- 2014A study on the synthesis of Ni50Co50 alloy nanostructures with tuned morphology through metal-organic chemical routescitations
- 2013PPH dendrimers grafted on silica nanoparticles: surface chemistry, characterization, silver colloids hosting and antibacterial activitycitations
- 2010Selective Vapor Sensing on Nanostructured SnO2 Materials: a global strategy approach
- 2009Size effects on varistor properties made from zinc oxide nanoparticles by low temperature spark plasma sintering
- 2009When Energetic Materials, PDMS-Based Elastomers, and Microelectronic Processes Work Together: Fabrication of a Disposable Microactuatorcitations
- 2009Size effect on properties of varistors made from zinc oxide nanoparticles through low temperature spark plasma sinteringcitations
- 2008Copper nanoparticles and organometallic chemical liquid deposition (OMCLD) for substrate metallizationcitations
Places of action
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article
Nano-Structuration of WO3 Nanoleaves by Localized Hydrolysis of an Organometallic Zn Precursor: Application to Photocatalytic NO2 Abatement
Abstract
<jats:p>WO3 is a known photocatalytic metal oxide frequently studied for its depollution properties. However, it suffers from a high recombination rate of the photogenerated electron/holes pair that is detrimental to its performance. In this paper, we present a new chemical method to decorate WO3 nanoleaves (NLs) with a complementary metal oxide (ZnWO4) in order to improve the photocatalytic performance of the composite material for the abatement of 400 ppb NO2 under mild UV exposure. Our strategy was to synthesize WO3·2H2O nanoleaves, then, to expose them, in water-free organic solution, to an organometallic precursor of Zn(Cy)2. A structural water molecule from WO3·2H2O spontaneously decomposes Zn(Cy)2 and induces the formation of the ZnO@WO3·H2O nanocomposite. The material was characterized by electronic microscopy (SEM, TEM), TGA, XRD, Raman and solid NMR spectroscopies. A simple thermal treatment under air at 500 °C affords the ZnWO4@WO3 nanocomposite. The resulting material, additionally decorated with 1% wt. Au, presents a remarkable increase (+166%) in the photocatalytic abatement of NO2 under UV compared to the pristine WO3 NLs. This synthesis method paves the way to the versatile preparation of a wide range of MOx@WO3 nanocomposites (MOx = metal oxide).</jats:p>