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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Bouich, Amal
Erasmus+
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (24/24 displayed)
- 2024From Powder Manufacturing to Perovskite/ i>p /i>-type TCO Thin Film Depositioncitations
- 2024Investigation of mixed bromide iodide lead perovskites by spin coating onto single and tandem solar cells applicationscitations
- 2024Advancements in bandgap engineering: bromide-doped cesium lead perovskite thin filmscitations
- 2024Growth and efficiency of MAPbBr3 based perovskite solar cells: insight from experimental and simulationcitations
- 2024Cu-Doped TiO sub>2 /sub> Thin Films by Spin Coating: Investigation of Structural and Optical Propertiescitations
- 2024Optical and morphological properties of DCM thin films co-doped of Znq2 by PVD: Theoretical and experimental investigationscitations
- 2023Bright future by enhancing the stability of methylammonium lead triiodide perovskites thin films through Rb, Cs and Li as dopantscitations
- 2023The Structural and Electrochemical Properties of CuCoO2 Crystalline Nanopowders and Thin Films: Conductivity Experimental Analysis and Insights from Density Functional Theory Calculationscitations
- 2023Bright future by controlling alpha/gamma phase junction of formamidinium lead iodide doped by imidazolium for solar cells: Insight from experimental, DFT calculations and SCAPS simulationcitations
- 2023Multifunctional cobalt oxide nanocomposites for efficient removal of heavy metals from aqueous solutionscitations
- 2023Surface engineering of zinc oxide thin as an electron transport layer for perovskite solar cellscitations
- 2023Removal of cadmium and lead ions from aqueous solutions by novel dolomite-quartz@Fe3O4 nanocomposite fabricated as nanoadsorbentcitations
- 2023Removal of cadmium and lead ions from aqueous solutions by novel dolomite-quartz@Fe3O4 nanocomposite fabricated as nanoadsorbentcitations
- 2023Surface Morphology And Optical Properties Of Ma-Doped Fapbbr3 Thin Films For Photovoltaic Applications
- 2023Optimization of the MA/FA Ratio in the Structure of Absorber Layers Based on MA(1-x)FAxPbI3 Perovskites for Stable and Efficient Solar Cellscitations
- 2023The structural and electrochemical properties of CuCoO2 crystalline nanopowders and thin films: conductivity experimental analysis and Insights from density functional theory calculationscitations
- 2022Manufacture of High-Efficiency and Stable Lead-Free Solar Cells through Antisolvent Quenching Engineeringcitations
- 2022Manufacture of High-Efficiency and Stable Lead-Free Solar Cells through Antisolvent Quenching Engineeringcitations
- 2022Tetrabutylammonium (TBA)-Doped Methylammonium Lead Iodide: High Quality and Stable Perovskite Thin Filmscitations
- 2022Stability Improvement of Methylammonium Lead Iodide Perovskite Thin Films by Bismuth Dopingcitations
- 2022Investigation of the Surface Coating, Humidity Degradation, and Recovery of Perovskite Film Phase for Solar-Cell Applicationscitations
- 2022Investigation of the Surface Coating, Humidity Degradation, and Recovery of Perovskite Film Phase for Solar-Cell Applicationscitations
- 2021Shedding Light on the Effect of Diethyl Ether Antisolvent on the Growth of (CH<SUB>3</SUB>NH<SUB>3</SUB>) PbI<SUB>3</SUB> Thin Filmscitations
- 2019Optoelectronic characterization of CuInGa(S)<SUB>2</SUB> thin films grown by spray pyrolysis for photovoltaic applicationcitations
Places of action
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article
Manufacture of High-Efficiency and Stable Lead-Free Solar Cells through Antisolvent Quenching Engineering
Abstract
<jats:p>Antisolvent quenching has shown to significantly enhance several perovskite films used in solar cells; however, no studies have been conducted on its impact on MASnI3. Here, we investigated the role that different antisolvents, i.e., diethyl ether, toluene, and chlorobenzene, have on the growth of MASnI3 films. The crystallinity, morphology, topography, and optical properties of the obtained thin films were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), photoluminescence (PL) measurements, and UV–visible spectroscopy. The impact of the different antisolvent treatments was evaluated based on the surface homogeneity as well as the structure of the MASnI3 thin films. In addition, thermal annealing was optimized to control the crystallization process. The applied antisolvent was modified to better manage the supersaturation process. The obtained results support the use of chlorobenzene and toluene to reduce pinholes and increase the grain size. Toluene was found to further improve the morphology and stability of thin films, as it showed less degradation after four weeks under dark with 60% humidity. Furthermore, we performed a simulation using SCAPS-1D software to observe the effect of these antisolvents on the performance of MASnI3-based solar cells. We also produced the device FTO/TiO2/MASnI3/Spiro-OMeTAD/Au, obtaining a remarkable photoconversion efficiency (PCE) improvement of 5.11% when using the MASnI3 device treated with chlorobenzene. A PCE improvement of 9.44% was obtained for the MASnI3 device treated with toluene, which also showed better stability. Our results support antisolvent quenching as a reproducible method to improve perovskite devices under ambient conditions.</jats:p>