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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Ünlü, Feray
Helmholtz-Zentrum Berlin für Materialien und Energie
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (7/7 displayed)
- 2023Electrospun Electroluminescent CsPbBr3 Fibers as Flexible Perovskite Networks for Light‐Emitting Applicationcitations
- 2022Electrospun Networks of ZnO-SnO2 Composite Nanowires as Electron Transport Materials for Perovskite Solar Cellscitations
- 2022Tantalum Oxide as an Efficient Alternative Electron Transporting Layer for Perovskite Solar Cellscitations
- 2022Thermally-induced drift of A-site cations at solid-solid interface in physically paired lead halide perovskitescitations
- 2021Roadmap on organic-inorganic hybrid perovskite semiconductors and devicescitations
- 2021Towards the environmentally friendly solution processing of metal halide perovskite technologycitations
- 2021Roadmap on organic–inorganic hybrid perovskite semiconductors and devicescitations
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article
Tantalum Oxide as an Efficient Alternative Electron Transporting Layer for Perovskite Solar Cells
Abstract
Electron transporting layers facilitating electron extraction and suppressing hole recombination at the cathode are crucial components in any thin-film solar cell geometry, including that of metal–halide perovskite solar cells. Amorphous tantalum oxide (Ta2O5) deposited by spin coating was explored as an electron transport material for perovskite solar cells, achieving power conversion efficiency (PCE) up to ~14%. Ultraviolet photoelectron spectroscopy (UPS) measurements revealed that the extraction of photogenerated electrons is facilitated due to proper alignment of bandgap energies. Steady-state photoluminescence spectroscopy (PL) verified efficient charge transport from perovskite absorber film to thin Ta2O5 layer. Our findings suggest that tantalum oxide as an n-type semiconductor with a calculated carrier density of ~7 × 1018/cm3 in amorphous Ta2O5 films, is a potentially competitive candidate for an electron transport material in perovskite solar cells.