Materials Map

Discover the materials research landscape. Find experts, partners, networks.

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The Materials Map is an open tool for improving networking and interdisciplinary exchange within materials research. It enables cross-database search for cooperation and network partners and discovering of the research landscape.

The dashboard provides detailed information about the selected scientist, e.g. publications. The dashboard can be filtered and shows the relationship to co-authors in different diagrams. In addition, a link is provided to find contact information.

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Materials Map under construction

The Materials Map is still under development. In its current state, it is only based on one single data source and, thus, incomplete and contains duplicates. We are working on incorporating new open data sources like ORCID to improve the quality and the timeliness of our data. We will update Materials Map as soon as possible and kindly ask for your patience.

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in Cooperation with on an Cooperation-Score of 37%

Topics

Publications (1/1 displayed)

  • 2021Optimization of Oxygen Evolution Reaction with Electroless Deposited Ni–P Catalytic Nanocoating24citations

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Chart of shared publication
Terrasi, Antonio
1 / 1 shared
Mirabella, Salvo
1 / 4 shared
Cosentino, Salvatore
1 / 1 shared
Battiato, Sergio Orazio
1 / 1 shared
Pellegrino, Anna Lucia
1 / 5 shared
Chart of publication period
2021

Co-Authors (by relevance)

  • Terrasi, Antonio
  • Mirabella, Salvo
  • Cosentino, Salvatore
  • Battiato, Sergio Orazio
  • Pellegrino, Anna Lucia
OrganizationsLocationPeople

article

Optimization of Oxygen Evolution Reaction with Electroless Deposited Ni–P Catalytic Nanocoating

  • Terrasi, Antonio
  • Mirabella, Salvo
  • Cosentino, Salvatore
  • Battiato, Sergio Orazio
  • Pellegrino, Anna Lucia
  • Urso, Mario
Abstract

<jats:p>The low efficiency of water electrolysis mostly arises from the thermodynamic uphill oxygen evolution reaction. The efficiency can be greatly improved by rationally designing low-cost and efficient oxygen evolution anode materials. Herein, we report the synthesis of Ni–P alloys adopting a facile electroless plating method under mild conditions on nickel substrates. The relationship between the Ni–P properties and catalytic activity allowed us to define the best conditions for the electroless synthesis of highperformance Ni–P catalysts. Indeed, the electrochemical investigations indicated an increased catalytic response by reducing the thickness and Ni/P ratio in the alloy. Furthermore, the Ni–P catalysts with optimized size and composition deposited on Ni foam exposed more active sites for the oxygen evolution reaction, yielding a current density of 10 mA cm−2 at an overpotential as low as 335 mV, exhibiting charge transfer resistances of only a few ohms and a remarkable turnover frequency (TOF) value of 0.62 s−1 at 350 mV. The present study provides an advancement in the control of the electroless synthetic approach for the design and large-scale application of high-performance metal phosphide catalysts for electrochemical water splitting.</jats:p>

Topics
  • density
  • nickel
  • Oxygen
  • current density