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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Kovnir, Kirill
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (13/13 displayed)
- 2024PbSe Quantum Dot Superlattice Thin Films for Thermoelectric Applicationscitations
- 2023Large-scale colloidal synthesis of chalcogenides for thermoelectric applicationscitations
- 2022High Seebeck coefficient from screen-printed colloidal PbSe nanocrystals thin filmcitations
- 2021Large-scale synthesis of semiconducting Cu(In,Ga)Se2 nanoparticles for screen printing applicationcitations
- 2021Compositional fluctuations mediated by excess tellurium in bismuth antimony telluride nanocomposite yields high thermoelectric performancecitations
- 2020Synergistic Computational-Experimental Discovery of Highly Selective PtCu Nanocluster Catalysts for Acetylene Semihydrogenationcitations
- 2020Scalable colloidal synthesis of Bi 2 Te 2.7 Se 0.3 plate-like particles give access to a high-performing n-type thermoelectric material for low temperature applicationcitations
- 2019Superstructural ordering in hexagonal CuInSe2 nanoparticlescitations
- 2018The Smaller the Better Hosting Trivalent Rare-Earth Guests in Cu-P Clathrate Cagescitations
- 2017High-efficiency thermoelectric Ba8Cu14Ge6P26 bridging the gap between tetrel-based and tetrel-free clathratescitations
- 2009Cationic Clathrate I Si46-xPxTey (6.6(1) < y < 7.5(1), x < 2y) : Crystal Structure, Homogeneity Range, and Physical Propertiescitations
- 2008The first silicon-based cationic clathrate III with high thermal stability: Si172-xPxTey (x=2y, y>20).citations
- 2007Sn20.5□3.5As22I8: A Largely Disordered Cationic Clathrate with a New Type of Superstructure and Abnormally Low Thermal Conductivitycitations
Places of action
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article
Large-scale synthesis of semiconducting Cu(In,Ga)Se2 nanoparticles for screen printing application
Abstract
During the last few decades, the interest over chalcopyrite and related photovoltaics has been growing due the outstanding structural and electrical properties of the thin-film Cu(In,Ga)Se 2 photoabsorber. More recently, thin film deposition through solution processing has gained increasing attention from the industry, due to the potential low-cost and high-throughput production. To this end, the elimination of the selenization procedure in the synthesis of Cu(In,Ga)Se 2 nanoparticles with following dispersion into ink formulations for printing/coating deposition processes are of high relevance. However, most of the reported syntheses procedures give access to tetragonal chalcopyrite Cu(In,Ga)Se 2 nanoparticles, whereas methods to obtain other structures are scarce. Herein, we report a large-scale synthesis of high-quality Cu(In,Ga)Se 2 nanoparticles with wurtzite hexagonal structure, with sizes of 10–70 nm, wide absorption in visible to near-infrared regions, and [Cu]/[In + Ga] ≈ 0.8 and [Ga]/[Ga + In] ≈ 0.3 metal ratios. The inclusion of the synthesized NPs into a water-based ink formulation for screen printing deposition results in thin films with homogenous thickness of ≈4.5 µm, paving the way towards environmentally friendly roll-to-roll production of photovoltaic systems. ; This research was funded by the Portuguese Foundation for Science and Technology (PTDC/CTM-ENE/5387/2014, PTDC/NAN-MAT/28745/2017, UID/FIS/04650/2020, UID/QUI/ 0686/2020, PTDC/FIS-MAC/28157/2017, POCI-01-0145-FEDER-028108, SFRH/BD/121780/2016); the Basque Government Industry Department (ELKARTEK, HAZITEK); the National Science Foundation (DMR-2003783 grant); the Search-ON2: revitalization of HPC infrastructure of UMinho, (NORTE07-0162-FEDER-000086), co-funded by the North Portugal Regional Operational Programme (ON.2-O Novo Norte), under the National Strategic Reference Framework (NSRF), through the European Regional Development Fund (ERDF). The use of the Advanced Photon Source, an Office of Science User Facility operated for the U.S. ...