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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Macutkevic, Jan
Center for Physical Sciences and Technology
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (25/25 displayed)
- 2023Multilayered Composites with Carbon Nanotubes for Electromagnetic Shielding Applicationcitations
- 2022Dielectric Properties of Hybrid Polyethylene Composites Containing Cobalt Nanoparticles and Carbon Nanotubescitations
- 2022Tannin-based resins for 3D printing of porous carbon architecturescitations
- 2022Electrical conductivity and dielectric relaxation in Ag1-xLixNbO3citations
- 2022Electrical Conductivity and Dielectric Relaxation in Ag1−xLixNbO3citations
- 2021Dielectric properties of PDMS composites filled with SrTiO 3 nanoparticlescitations
- 2021Fibers of Thermoplastic Copolyamides with Carbon Nanotubes for Electromagnetic Shielding Applicationscitations
- 2021Dielectric Relaxation Spectroscopy and Synergy Effects in Epoxy/MWCNT/Ni@C Compositescitations
- 2020Crossover from Ferroelectric to Relaxor Behavior in Ba1−xCaxTiO3 (x = 0.17) Systemcitations
- 2020Dielectric Relaxation in the Hybrid Epoxy/MWCNT/MnFe2O4 Compositescitations
- 2020Electrical percolation and electromagnetic properties of polydimethylsiloxane composites filled with Ag nanoparticles of different sizescitations
- 2020THz Spectroscopy as a Versatile Tool for Filler Distribution Diagnostics in Polymer Nanocompositescitations
- 2019Fine Tuning of Electrical Transport and Dielectric Properties of Epoxy/Carbon Nanotubes Composites via Magnesium Oxide Additivescitations
- 2019Electromagnetic Properties of Carbon Gelscitations
- 2019Broadband Dielectric Properties of Fe<sub>2</sub>O<sub>3</sub>·H<sub>2</sub>O Nanorods/Epoxy Resin Compositescitations
- 2019Electromagnetics of carbon: Nano versus microcitations
- 2019Broadband Dielectric Properties of Fe2O3·H2O Nanorods/Epoxy Resin Compositescitations
- 2019Dielectric Properties of Epoxy-Matrix Composites with Tungsten Disulfide Nanotubescitations
- 2018Size-dependent electrical and thermal properties of onion-like carbons / polyurethane compositescitations
- 2018Influence of carbon nanotube surface treatment on resistivity and low‐frequency noise characteristics of epoxy‐based compositescitations
- 2018Hot-melt adhesives based on co-polyamide and multiwalled carbon nanotubescitations
- 2015Ultrasonic and dielectric relaxations in PDMS/ZnO nanocompositecitations
- 2015Synergy effects in the electrical conductivity behavior of onion-like carbon and multiwalled carbon nanotubes compositescitations
- 2014Dielectric properties of graphite-based epoxy compositescitations
- 2010Terahertz sensing with carbon nanotube layers coated on silica fibers: Carrier transport versus nanoantenna effectscitations
Places of action
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article
Dielectric Relaxation Spectroscopy and Synergy Effects in Epoxy/MWCNT/Ni@C Composites
Abstract
<jats:p>The dielectric/electric properties of the Ni@C (carbon-coated Ni)/epoxy composites and Ni@C/MWCNTs (multi-walled carbon nanotubes)/epoxy composites loaded with fixed MWCNTs amount just below the percolation threshold (0.09 vol.%) and Ni@C at different concentrations up to 1 vol.% were investigated in broad frequency (20 Hz–40 GHz) and temperature (30 K–500 K) regions. In composites with the only Ni@C nanoparticles, the electrical percolation threshold was determined between 10 and 15 vol.%. Above the percolation threshold the dielectric permittivity (ε’) and the electrical conductivity (σ) of the composites loaded with Ni@C only are high enough, i.e., ε’ = 105 and σ = 0.6 S/m at 100 Hz for composites with 30 vol.% Ni@C, to be used for electromagnetic shielding applications. The annealing to 500 K was proved to be an effective and simple tool to decrease the percolation threshold in epoxy/Ni@C composites. For hybrid composites series an optimal concentration of Ni@C (0.2 vol.%) was determined, leading to the conductivity absolute values several orders of magnitude higher than that of a composite filled with MWCNTs only. The synergy effects of using both fillers have been discussed. Below room temperature the electrical transport is mainly governed by epoxy resin compression in all composites, while the electron tunnelling was observed only in hybrid composites below 200 K. At higher temperatures (above 400 K), in addition to the nanoparticles redistribution effects, the electrical conductivity of epoxy resin makes a significant contribution to the total composite conductivity. The dielectric relaxation spectroscopy allows estimating the nanoparticles distributions in polymer matrix and could be used as the non-destructive and fast alternate to microscopy techniques for general polymer composite fabrication control.</jats:p>