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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Meisak, Darya
Vilnius University
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (8/8 displayed)
- 2024Effect of Particle Size on the Origin of Electromechanical Response in BaTiO 3 /PDMS Nanogeneratorscitations
- 2021Hybrid multifunctional composites with nanoinclusions and structures for electromagnetic applications / ; Hibrdiniai multifunkciniai kompozitai su nanodariniais ir struktūros elektromagnetiniams taikymams.
- 2021Dielectric Relaxation Spectroscopy and Synergy Effects in Epoxy/MWCNT/Ni@C Compositescitations
- 2020Dielectric Relaxation in the Hybrid Epoxy/MWCNT/MnFe2O4 Compositescitations
- 2019Fine Tuning of Electrical Transport and Dielectric Properties of Epoxy/Carbon Nanotubes Composites via Magnesium Oxide Additivescitations
- 2019Broadband Dielectric Properties of Fe<sub>2</sub>O<sub>3</sub>·H<sub>2</sub>O Nanorods/Epoxy Resin Compositescitations
- 2019Broadband Dielectric Properties of Fe2O3·H2O Nanorods/Epoxy Resin Compositescitations
- 2018Morphological, Rheological and Electromagnetic Properties of Nanocarbon/Poly(lactic) Acid for 3D Printing: Solution Blending vs. Melt Mixingcitations
Places of action
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article
Dielectric Relaxation Spectroscopy and Synergy Effects in Epoxy/MWCNT/Ni@C Composites
Abstract
<jats:p>The dielectric/electric properties of the Ni@C (carbon-coated Ni)/epoxy composites and Ni@C/MWCNTs (multi-walled carbon nanotubes)/epoxy composites loaded with fixed MWCNTs amount just below the percolation threshold (0.09 vol.%) and Ni@C at different concentrations up to 1 vol.% were investigated in broad frequency (20 Hz–40 GHz) and temperature (30 K–500 K) regions. In composites with the only Ni@C nanoparticles, the electrical percolation threshold was determined between 10 and 15 vol.%. Above the percolation threshold the dielectric permittivity (ε’) and the electrical conductivity (σ) of the composites loaded with Ni@C only are high enough, i.e., ε’ = 105 and σ = 0.6 S/m at 100 Hz for composites with 30 vol.% Ni@C, to be used for electromagnetic shielding applications. The annealing to 500 K was proved to be an effective and simple tool to decrease the percolation threshold in epoxy/Ni@C composites. For hybrid composites series an optimal concentration of Ni@C (0.2 vol.%) was determined, leading to the conductivity absolute values several orders of magnitude higher than that of a composite filled with MWCNTs only. The synergy effects of using both fillers have been discussed. Below room temperature the electrical transport is mainly governed by epoxy resin compression in all composites, while the electron tunnelling was observed only in hybrid composites below 200 K. At higher temperatures (above 400 K), in addition to the nanoparticles redistribution effects, the electrical conductivity of epoxy resin makes a significant contribution to the total composite conductivity. The dielectric relaxation spectroscopy allows estimating the nanoparticles distributions in polymer matrix and could be used as the non-destructive and fast alternate to microscopy techniques for general polymer composite fabrication control.</jats:p>