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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Santos, Lmnbf
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (23/23 displayed)
- 2023Confined Silver Nanoparticles in Ionic Liquid Filmscitations
- 2022Ohmic heating-assisted synthesis and characterization of Zn(ii), Cu(ii) and Pd(ii) complexes of heterocyclic-fused chlorinscitations
- 2022The impact of the cation alkyl chain length on the wettability of alkylimidazolium-based ionic liquids at the nanoscalecitations
- 2022Extensive characterization of choline chloride and its solid-liquid equilibrium with watercitations
- 2022Enthalpy of solvation of alkali metal salts in a protic ionic liquid: Effect of cation charge and sizecitations
- 2022Solid-Liquid-Gas Phase Equilibria for Small Phenylene-Thiophene Co-Oligomerscitations
- 2022The effect of oxidation state and tert-butyl substituents on the thermal behavior and thin-film morphology of cobalt-complexes (FK 102 and FK 209)citations
- 2021On the Aromatic Stabilization of Fused Polycyclic Aromatic Hydrocarbonscitations
- 2020Morphology, Structure, and Dynamics of Pentacene Thin Films and Their Nanocomposites with [C(2)C(1)im][NTf2] and [C(2)C(1)im][OTF] Ionic Liquidscitations
- 2019Synthesis of Pyridyl and N-Methylpyridinium Analogues of Rosamines: Relevance of Solvent and Charge on Their Photophysical Propertiescitations
- 2019Oxidative Treatment of Multi-Walled Carbon Nanotubes and its Effect on the Mechanical and Electrical Properties of Green Epoxy based Nano-Compositescitations
- 2018High purity and crystalline thin films of methylammonium lead iodide perovskites by a vapor deposition approachcitations
- 2018Thin film deposition of organic hole transporting materials: optical, thermodynamic and morphological properties of naphthyl-substituted benzidinescitations
- 2018Nucleation and growth of microdroplets of ionic liquids deposited by physical vapor method onto different surfacescitations
- 2017On the Deposition of Lead Halide Perovskite Precursors by Physical Vapor Methodcitations
- 2016Morphology of Imidazolium-Based Ionic Liquids as Deposited by Vapor Deposition: Micro-/Nanodroplets and Thin Filmscitations
- 2016The effect of n vs. iso isomerization on the thermophysical properties of aromatic and non-aromatic ionic liquidscitations
- 2015Description and Test of a New Multilayer Thin Film Vapor Deposition Apparatus for Organic Semiconductor Materialscitations
- 2007Thermochemical studies of five crystalline bis(O-alkyl-N-thenoylthiocarbamato)nickel(II) complexescitations
- 2004Standard molar enthalpies of formation of two crystalline bis[N-(diethylaminothiocarbonyl)benzamidinato]nickel(II) complexescitations
- 2004Standard molar enthalpies of formation of two crystalline bis[N-(diethylaminothiocarbonyl)benzamidinato]nickel(II) complexescitations
- 2004Thermodynamics of the interaction between a hydrophobically modified polyelectrolyte and sodium dodecyl sulfate in aqueous solutioncitations
- 2004Thermochemical studies of three bis(O-alkyl-N-benzoylthiocarbamato)nickel(II) complexescitations
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article
Confined Silver Nanoparticles in Ionic Liquid Films
Abstract
This work reports the formation of silver nanoparticles (AgNPs) by sputter deposition in thin films of three different ionic liquids (ILs) with the same anion (bis(trifluoromethylsulfonyl)imide) and cation (imidazolium), but with different alkyl chain lengths and symmetries in the cationic moiety ([C(4)C(1)im][NTf2], [C(2)C(2)im][NTf2], and [C(5)C(5)im][NTf2]). Ionic liquid (IL) films in the form of microdroplets with different thicknesses (200 to 800 monolayers) were obtained through vacuum thermal evaporation onto glass substrates coated with indium tin oxide (ITO). The sputtering process of the Ag onto the ILs when conducted simultaneously with argon plasma promoted the coalescence of the ILs' droplets and the formation, incorporation, and stabilization of the metallic nanoparticles in the coalesced IL films. The formation/stabilization of the AgNPs in the IL films was confirmed using high-resolution scanning electron microscopy (SEM) and UV-Vis spectroscopy. It was found that the IL films with larger thicknesses (600 and 800 monolayers) were better media for the formation of AgNPs. Among the ILs used, [C(5)C(5)im][NTf2] was found to be particularly promising for the stabilization of AgNPs. The use of larger IL droplets as capture media was found to promote a better stabilization of the AgNPs, thereby reducing their tendency to aggregate.