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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Llorca, Jordi
Universitat Politècnica de Catalunya
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (16/16 displayed)
- 2024Chemical etching optimization of 3D printed a-Al2O3 monoliths to enhance the catalytic applications
- 2023Nanoshaped Cerium Oxide with Nickel as a Non-Noble Metal Catalyst for CO2 Thermochemical Reactionscitations
- 2023Facet-engineered TiO2 drives photocatalytic activity and stability of supported noble metal clusters during H2 evolution
- 2023Exsolution-enhanced reverse water-gas shift chemical looping activity of Sr2FeMo0.6Ni0.4O6-δ double perovskitecitations
- 2021Ligand conversion in nanocrystal synthesis: The oxidation of alkylamines to fatty acids by nitratecitations
- 2020Hydrogen photogeneration using ternary CuGaS2-TiO2-Pt nanocompositescitations
- 2020CO total and preferential oxidation over stable Au/TiO2 catalysts derived from preformed Au nanoparticlescitations
- 2019Hollow PdAg-CeO2 heterodimer nanocrystals as highly structured heterogeneous catalysts
- 2019Hollow PdAg-CeO2 heterodimer nanocrystals as highly structured heterogeneous catalystscitations
- 2019Reactivity assessment and oxidation kinetic model for CO2 splitting on Fe-based oxygen carrier
- 2017Inside Cover: Surface Faceting and Reconstruction of Ceria Nanoparticles (Angew. Chem. Int. Ed. 1/2017)citations
- 2017Role of the synthesis route on the properties of hybrid LDH-graphene as basic catalysts.citations
- 2017Enhanced photocatalytic degradation of methylene blue: Preparation of TiO2/reduced graphene oxide nanocomposites by direct sol-gel and hydrothermal methodscitations
- 2017Surface Faceting and Reconstruction of Ceria Nanoparticlescitations
- 2016Synthesis and thermoelectric properties of noble metal ternary chalcogenide systems of Ag–Au–Se in the forms of alloyed nanoparticles and colloidal nanoheterostructurescitations
- 2013A general approach to fabricate Fe 3 O 4 nanoparticles decorated with Pd, Au, and Rh: magnetically recoverable and reusable catalysts for Suzuki CC cross-coupling reactions, hydrogenation, and sequential reactionscitations
Places of action
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article
Nanoshaped Cerium Oxide with Nickel as a Non-Noble Metal Catalyst for CO2 Thermochemical Reactions
Abstract
<jats:p>Four different nanoshapes of cerium dioxide have been prepared (polycrystals, rods, cubes, and octahedra) and have been decorated with different metals (Ru, Pd, Au, Pt, Cu, and Ni) by incipient wetness impregnation (IWI) and ball milling (BM) methods. After an initial analysis based on oxygen consumption from CO2 pulse chemisorption, Ni-like metal, and two forms of CeO2 cubes and rods were selected for further research. Catalysts were characterized using the Brunauer-Emmett-Teller formula (BET), X-ray spectroscopy (XRD), Raman spectroscopy, scanning electron microscopy (SEM), UV–visible spectrophotometry (UV-Vis), X-ray photoelectron spectroscopy (XPS), temperature programmed reduction (H2-TPR) and CO2 pulse chemisorption, and used to reduce of CO2 into CO (CO2 splitting). Adding metals to cerium dioxide enhanced the ability of CeO2 to release oxygen and concomitant reactivity toward the reduction of CO2. The effect of the metal precursor and concentration were evaluated. The highest CO2 splitting value was achieved for 2% Ni/CeO2-rods prepared by ball milling using Ni nitrate (412 µmol/gcat) and the H2 consumption (453.2 µmol/gcat) confirms the good redox ability of this catalyst.</jats:p>