| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Janiak, Christoph
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (14/14 displayed)
- 2023Synthesis of Ketjenblack Decorated Pillared Ni(Fe) Metal-Organic Frameworks as Precursor Electrocatalysts for Enhancing the Oxygen Evolution Reactioncitations
- 2023Formation of Gold Nanoclusters from Goldcarbonyl Chloride inside the Metal-Organic Framework HKUST-1citations
- 2022Synthesis of tin nanoparticles on Ketjen Black in ionic liquid and water for the hydrogen evolution reactioncitations
- 2022A diamantane-4,9-dicarboxylate based UiO-66 analogue: challenging larger hydrocarbon cage platforms ; Diamantan-4,9-dikarboxylát založení na UiO-66 analogu: náročnější na rozsáhlé uhlovodíkové strukturní platformycitations
- 2021Nickel nanoparticle-decorated reduced graphene oxide/WO3 nanocomposite – a promising candidate for gas sensingcitations
- 2020Synthesis of plasmonic Fe/Al nanoparticles in ionic liquidscitations
- 2020Amino-functionalized MIL-101(Cr) photodegradation enhancement by sulfur-enriched copper sulfide nanoparticles: an experimental and DFT studycitations
- 2019A metal-organic framework for efficient water-based ultra-low-temperature-driven coolingcitations
- 2018Synthesis of rare-earth metal and rare-earth metal-fluoride nanoparticles in ionic liquids and propylene carbonatecitations
- 2017Soft, Wet-Chemical Synthesis of Metastable Superparamagnetic Hexagonal Close-Packed Nickel Nanoparticles in Different Ionic Liquidscitations
- 2017Synthesis of Metal Nanoparticles and Metal Fluoride Nanoparticles from Metal Amidinate Precursors in 1-Butyl-3-Methylimidazolium Ionic Liquids and Propylene Carbonatecitations
- 2016Use of a 4,5-dicyanoimidazolate anion based ionic liquid for the synthesis of iron and silver nanoparticlescitations
- 2015Bis((dialkylamino)alkylselenolato)metal complexes as precursors for microwave-assisted synthesis of semiconductor metal selenide nanoparticles of zinc and cadmium in the ionic liquid [BMIm][ BF4]citations
- 2010Microwave irradiation for the facile synthesis of transition-metal nanoparticles (NPs) in ionic liquids (ILs) from metal-carbonyl precursors and Ru-, Rh-, and Ir-NP/IL dispersions as biphasic liquid-liquid hydrogenation nanocatalysts for cyclohexenecitations
Places of action
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article
Formation of Gold Nanoclusters from Goldcarbonyl Chloride inside the Metal-Organic Framework HKUST-1
Abstract
Gas-phase infiltration of the carbonylchloridogold(I), Au(CO)Cl precursor into the pores of HKUST-1 ([Cu$_3$(BTC)$_2$(H$_2$O)$_2$], Cu-BTC) SURMOFs (surface-mounted metal-organic frameworks; BTC = benzene-1,3,5-tricarboxylate) leads to Au(CO)Cl decomposition within the MOF through hydrolysis with the aqua ligands on Cu. Small Au$_x$ clusters with an average atom number of x ≈ 5 are formed in the medium-sized pores of the HKUST-1 matrix. These gold nanoclusters are homogeneously distributed and crystallographically ordered, which was supported by simulations of the powder X-ray diffractometric characterization. Au$_x$@HKUST-1 was further characterized by scanning electron microscopy (SEM) and infrared reflection absorption (IRRA) as well as Raman spectroscopy, time-of-flight secondary ion mass spectrometry (ToF-SIMS), X-ray photoelectron spectroscopy (XPS) and inductively coupled plasma optical emission spectroscopy (ICP-OES).