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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Baran, Stanisław
Jagiellonian University
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (13/13 displayed)
- 2024Investigation of glass transition and polymorphism of smectogenic, partially fluorinated chiral compound by X-ray diffraction and infra-red spectroscopycitations
- 2024The crystal and electronic structure of RE$_{23}$Co$_{6.7}$In$_{20.3}$ (RE = Gd–Tm, Lu) : a new structure type based on intergrowth of AlB$_{2}$- and CsCl-type related slabscitations
- 2024The crystal and electronic structure of RE23Co6.7In20.3 (RE = Gd–Tm, Lu)citations
- 2022An intermetallic molecular nanomagnet with the lanthanide coordinated only by transition metalscitations
- 2022The High-Temperature Soft Ferromagnetic Molecular Materials Based on [W(CN)6(bpy)]2−/− Systemcitations
- 2022Tuning magnetostructural phase transition in $CoMn_{0.88}Cu_{0.12}Ge$ by application of hydrostatic pressurecitations
- 2022The high-temperature soft ferromagnetic molecular materials based on $[W(CN)_{6}(bpy)]^{2-/-}$ systemcitations
- 2021Complex magnetic ordering in $RE_{5}Pd_{2}In_{4}$ (RE = Tb-Tm) compounds investigated by neutron diffraction and magnetometric measurementscitations
- 2020Magnetic properties and magnetic structures of R_{2}PdGe_{6} (R = Pr, Nd, Gd-Er) and R_{2}PtGe_{6} (R = Tb, Ho, Er)citations
- 2014Neutron diffraction studies of NdNi_{5}Sn compoundcitations
- 2014Neutron diffraction studies of nanoparticle DyMnO_{3} compoundcitations
- 2012Structural chemistry and magnetic properties of $R_{11}M_{4}In_{6}$ (R = Gd, Tb, Dy, Ho, Er, Y; M = Si, Ge) compoundscitations
- 2010Magnetic ordering and magnetic properties of $ErAu_{x}Ni_{1−x}In left ( 0leq xleq 1 right )$ solid solutioncitations
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article
The High-Temperature Soft Ferromagnetic Molecular Materials Based on [W(CN)6(bpy)]2−/− System
Abstract
<jats:p>The synthesis of molecular materials with magnetic properties, in particular ferromagnetic properties, has been the subject of interest in coordination chemistry for decades. In the last three decades, research has accelerated, as it has emerged that creating bridging systems based on cyanido ligands is a good and relatively simple way to create complex polymer structures exhibiting magnetic properties. Based on many years of personal experience in the field of the synthesis of polycyanido systems, supported by comprehensive structural analysis, a simple method of transforming cyanido complexes into soft ferromagnetic materials with a Curie temperature (TC) higher than the thermal decomposition temperature, usually above 150 °C has been developed. Two soft ferromagnetic materials based on zinc and cadmium hexacyanido salts in the system with [W(CN)6(bpy)]2−/− anions are presented. The crystal structures (X-ray single crystal as well as XRD) of the precursors and the properties of the ferromagnetic materials are discussed. Most importantly, a patented method of synthesizing this type of material, based on which we obtain more than 80 soft, high-temperature ferromagnetic compounds, which proves the wide spectrum of this method, is also presented.</jats:p>