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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Fliri, Lukas
Aalto University
in Cooperation with on an Cooperation-Score of 37%
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Publications (4/4 displayed)
- 2024Applications of NMR based methodologies investigating the behavior of lignin and cellulose towards bio-based carbon fibers production
- 2024Viscoelastic phenomena in methylcellulose aqueous systems : Application of fractional calculuscitations
- 2024Viscoelastic phenomena in methylcellulose aqueous systems:Application of fractional calculuscitations
- 2022A Fluoroponytailed NHC–Silver Complex Formed from Vinyl-imidazolium/AgNO3 under Aqueous– Ammoniacal Conditionscitations
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article
A Fluoroponytailed NHC–Silver Complex Formed from Vinyl-imidazolium/AgNO3 under Aqueous– Ammoniacal Conditions
Abstract
Publisher Copyright: © 2022 by the authors. Licensee MDPI, Basel, Switzerland. ; 3-(1H,1H,2H,2H-Perfluorooctyl)-1-vinylimidazolium chloride [2126844–17–3], a strong fluorosurfactant with remarkably high solubility in water, was expediently converted into the respective doubly NHC-complexed silver salt with nitrate as counter ion in quantitative yield. Due to its vinyl substituents, [bis(3-(1H,1H,2H,2H-perfluorooctyl)-1-vinylimidazol-2-ylidene)silver(I)] nitrate, Ag(FNHC)2NO3, represents a polymerizable N-heterocyclic carbene transfer reagent, thus potentially offering simple and robust access to coordination polymers with crosslinking metal bridges. The compound was characterized by infrared and NMR spectroscopy, mass spectrometry as well as elemental analysis, and supplemented by X-ray single-crystal structure determination. It crystallizes in the monoclinic crystal system in the space group P21/c. With 173.3◦, the geometry of the Ag-carbene bridge deviates slightly from linearity. The disordered perfluoroalkyl side chains exhibit a helical conformation. ; Peer reviewed