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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Raja, Robert
University of Southampton
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (9/9 displayed)
- 2023Using small angle neutron scattering to explore porosity, connectivity and accessibility, towards optimised hierarchical solid acid catalystscitations
- 2022New insights in establishing the structure-property relations of novel plasmonic nanostructures for clean energy applicationscitations
- 2021Rational design and application of covalent organic frameworks for solar fuel productioncitations
- 2020Combining photocatalysis and optical fibre technology towards improved microreactor design for hydrogen generation with metallic nanoparticlescitations
- 2020Incorporating metal organic frameworks within microstructured optical fibers toward scalable photoreactorscitations
- 2017Heterogeneous zeotype catalysts for the direct utilisation of CO2
- 2017The molecular design of active sites in nanoporous materials for sustainable catalysiscitations
- 2013Investigating site-specific interactions and probing their role in modifying the acid-strength in framework architecturescitations
- 2009Designed nanoporous solids for the green production of vitamins, fine chemicals and renewable nylonscitations
Places of action
Organizations | Location | People |
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article
Rational design and application of covalent organic frameworks for solar fuel production
Abstract
Harnessing solar energy and converting it into renewable fuels by chemical processes, such as water splitting and carbon dioxide (CO<sub>2</sub>) reduction, is a highly promising yet challenging strategy to mitigate the effects arising from the global energy crisis and serious environmental concerns. In recent years, covalent organic framework (COF)-based materials have gained substantial research interest because of their diversified architecture, tunable composition, large surface area, and high thermal and chemical stability. Their tunable band structure and significant light absorption with higher charge separation efficiency of photoinduced carriers make them suitable candidates for photocatalytic applications in hydrogen (H<sub>2</sub>) generation, CO<sub>2</sub> conversion, and various organic transformation reactions. In this article, we describe the recent progress in the topology design and synthesis method of COF-based nanomaterials by elucidating the structure-property correlations for photocatalytic hydrogen generation and CO<sub>2</sub> reduction applications. The effect of using various kinds of 2D and 3D COFs and strategies to control the morphology and enhance the photocatalytic activity is also summarized. Finally, the key challenges and perspectives in the field are highlighted for the future development of highly efficient COF-based photocatalysts.