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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Laversenne, Laetitia
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Topics
Publications (9/9 displayed)
- 2022Hydrogen Storage Properties of a New Ti-V-Cr-Zr-Nb High Entropy Alloycitations
- 2021Hydrogen Sorption Properties of a Novel Refractory Ti-V-Zr-Nb-Mo High Entropy Alloycitations
- 2021How 10 at% Al Addition in the Ti-V-Zr-Nb High-Entropy Alloy Changes Hydrogen Sorption Propertiescitations
- 2020Hydrogen Storage Properties of Mg-Ni Alloys Processed by Fast Forgingcitations
- 2020Improving hydrogen storage performance of Mg-based alloy through microstructure optimizationcitations
- 2019Three-phase metal-insulator transition and structural alternative for a VO2 film epitaxially grown on Al2O3(0001)citations
- 2019TiVZrNb Multi-Principal-Element Alloy: Synthesis Optimization, Structural, and Hydrogen Sorption Propertiescitations
- 2019TiVZrNb Multi-Principal-Element Alloy : Synthesis Optimization, Structural, and Hydrogen Sorption Propertiescitations
- 2016Multi-scale architectured thermoelectric materials in the Mg2(Si,Sn) systemcitations
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article
How 10 at% Al Addition in the Ti-V-Zr-Nb High-Entropy Alloy Changes Hydrogen Sorption Properties
Abstract
<jats:p>Al0.10Ti0.30V0.25Zr0.10Nb0.25 was prepared to evaluate the effect of 10% aluminum into the previously reported quaternary alloy, Ti0.325V0.275Zr0.125Nb0.275. The as-cast quinary alloy formed a single-phase body centered cubic solid solution and transformed into a body centered tetragonal after hydrogenation. The alloy had a storage capacity of 1.6 H/M (2.6 wt.%) with fast absorption kinetics at room temperature, reaching full capacity within the first 10 min. The major improvements of Al addition (10%) were related to the desorption and cycling properties of the material. The temperature for hydrogen release was significantly decreased by around 100 °C, and the quinary alloy showed superior cycling stability and higher reversible storage capacity than its quaternary counterpart, 94% and 85% of their respective initial capacity, after 20 hydrogenation cycles without phase decomposition.</jats:p>