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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Katerski, Atanas
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Publications (9/9 displayed)
- 2024An Alternative Chlorine-Assisted Optimization of CdS/Sb2Se3 Solar Cellscitations
- 2023Combinative solution processing and Li doping approach to develop p-type NiO thin films with enchanced electrical propertiescitations
- 2020Application of ultrasonic sprayed zirconium oxide dielectric in zinc tin oxide-based thin film transistorcitations
- 2019Uniform Sb<sub>2</sub>S<sub>3</sub>optical coatings by chemical spray methodcitations
- 2019Influence of Post-UV/Ozone Treatment of Ultrasonic-Sprayed Zirconium Oxide Dielectric Films for a Low-Temperature Oxide Thin Film Transistorcitations
- 2019Photocatalytic Degradation of Different VOCs in the Gas-Phase over TiO2 Thin Films Prepared by Ultrasonic Spray Pyrolysiscitations
- 2019Effect of the Titanium Isopropoxide:Acetylacetone Molar Ratio on the Photocatalytic Activity of TiO2 Thin Filmscitations
- 2019Semitransparent Sb2S3 thin film solar cells by ultrasonic spray pyrolysis for use in solar windowscitations
- 2016Tin sulfide films by spray pyrolysis technique using L‐cysteine as a novel sulfur sourcecitations
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article
Effect of the Titanium Isopropoxide:Acetylacetone Molar Ratio on the Photocatalytic Activity of TiO2 Thin Films
Abstract
<jats:p>TiO2 thin films with different titanium isopropoxide (TTIP):acetylacetone (AcacH) molar ratios in solution were prepared by the chemical spray pyrolysis method. The TTIP:AcacH molar ratio in spray solution varied from 1:3 to 1:20. TiO2 films were deposited onto the glass substrates at 350 °C and heat-treated at 500 °C. The morphology, structure, surface chemical composition, and photocatalytic activity of the obtained TiO2 films were investigated. TiO2 films showed a transparency of ca 80% in the visible spectral region and a band gap of ca 3.4 eV irrespective of the TTIP:AcacH molar ratio in the spray solution. TiO2 films consist of the anatase crystalline phase with a mean crystallite size in the range of 30–40 nm. Self-cleaning properties of the films were estimated using the stearic acid (SA) test. A thin layer of 8.8-mM SA solution was spin-coated onto the TiO2 film. The degradation rate of SA as a function of irradiation time was monitored by Fourier-transform infrared spectroscopy (FTIR). An increase in the TTIP:AcacH molar ratio from 1:4 to 1:8 resulted in a ten-fold increase in the photodegradation reaction rate constant (from 0.02 to the 0.2 min−1) under ultraviolet light and in a four-fold increase under visible light.</jats:p>