| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Papadopoulos, Lazaros
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (11/11 displayed)
- 2024Influence of reactive diluent composition on properties and bio-based content of itaconic acid-based additive manufacturing materialscitations
- 2024Itaconic acid-based 3D printed nanocomposites: An in-depth study on the effect of nanoinclusions on the physicochemical properties and the printability of formulations based on polyester itaconatescitations
- 2024Melting Behavior of Compression Molded Poly(ester amide) from 2,5-Furandicarboxylic Acid
- 2023Bio-based additive manufacturing materials: An in-depth structure-property relationship study of UV-curing polyesters from itaconic acidcitations
- 2021Comparative study of crystallization, semicrystalline morphology, and molecular mobility in nanocomposites based on polylactide and various inclusions at low filler loadingscitations
- 2021Synthesis and Characterization of Unsaturated Succinic Acid Biobased Polyester Resinscitations
- 2021Properties of poly(lactic acid)/montmorillonite/carbon nanotubes nanocomposites: determination of percolation thresholdcitations
- 2021Bottom-up development of nanoimprinted PLLA composite films with enhanced antibacterial properties for smart packaging applicationscitations
- 2021Bottom-up development of nanoimprinted PLLA composite films with enhanced antibacterial properties for smart packaging applicationscitations
- 2019Thermal Decomposition Kinetics and Mechanism of In-Situ Prepared Bio-based Poly(propylene 2,5-furan dicarboxylate)/Graphene Nanocompositescitations
- 2018Synthesis and characterization of in-situ-prepared nanocomposites based on poly(propylene 2,5-furan dicarboxylate) and aluminosilicate clayscitations
Places of action
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article
Thermal Decomposition Kinetics and Mechanism of In-Situ Prepared Bio-based Poly(propylene 2,5-furan dicarboxylate)/Graphene Nanocomposites
Abstract
<jats:p>Bio-based polyesters are a new class of materials that are expected to replace their fossil-based homologues in the near future. In this work, poly(propylene 2,5-furandicarboxylate) (PPF) nanocomposites with graphene nanoplatelets were prepared via the in-situ melt polycondensation method. The chemical structure of the resulting polymers was confirmed by 1H-NMR spectroscopy. Thermal stability, decomposition kinetics and the decomposition mechanism of the PPF nanocomposites were studied in detail. According to thermogravimetric analysis results, graphene nanoplatelets did nοt affect the thermal stability of PPF at levels of 0.5, 1.0 and 2.5 wt.%, but caused a slight increase in the activation energy values. Pyrolysis combined with gas chromatography and mass spectroscopy revealed that the decomposition mechanism of the polymer was not altered by the presence of graphene nanoplatelets but the extent of secondary homolytic degradation reactions was increased.</jats:p>