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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Gili, Albert
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (11/11 displayed)
- 2023Revealing the Chemical State of Palladium in Operating In2O3 Gas Sensors: Metallic Pd Enhances Sensing Response and Intermetallic InxPdy Compound Blocks It
- 2022Atomic-Scale Insights into Nickel Exsolution on LaNiO 3 Catalysts via In Situ Electron Microscopycitations
- 2022Clay in situ resource utilization with Mars global simulant slurries for additive manufacturing and traditional shaping of unfired green bodies
- 2021Steering the methanol steam reforming reactivity of intermetallic Cu–In compounds by redox activation: stability vs. formation of an intermetallic compound–oxide interfacecitations
- 2021Mechanistic in situ insights into the formation, structural and catalytic aspects of the La2NiO4 intermediate phase in the dry reforming of methane over Ni-based perovskite catalystscitations
- 2021Silicon oxycarbonitride ceramic containing nickel nanoparticles: from design to catalytic applicationcitations
- 2021The sol–gel autocombustion as a route towards highly CO 2 -selective, active and long-term stable Cu/ZrO 2 methanol steam reforming catalystscitations
- 2020Sintering of ceramics for clay in situ resource utilization on Mars
- 2020Ceria-Based Dual-Phase Membranes for High-Temperature Carbon Dioxide Separation: Effect of Iron Doping and Pore Generation with MgO Template
- 2019Ceria-Based Dual-Phase Membranes for High-Temperature Carbon Dioxide Separation: Effect of Iron Doping and Pore Generation with MgO Templatecitations
- 2018Formation of Pd-Ce intermetallic compounds by reductive metal-support interactioncitations
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article
Ceria-Based Dual-Phase Membranes for High-Temperature Carbon Dioxide Separation: Effect of Iron Doping and Pore Generation with MgO Template
Abstract
<jats:p>Dual-phase membranes for high-temperature carbon dioxide separation have emerged as promising technology to mitigate anthropogenic greenhouse gases emissions, especially as a pre- and post-combustion separation technique in coal burning power plants. To implement these membranes industrially, the carbon dioxide permeability must be improved. In this study, Ce0.8Sm0.2O2−δ (SDC) and Ce0.8Sm0.19Fe0.01O2−δ (FSDC) ceramic powders were used to form the skeleton in dual-phase membranes. The use of MgO as an environmentally friendly pore generator allows control over the membrane porosity and microstructure in order to compare the effect of the membrane’s ceramic phase. The ceramic powders and the resulting membranes were characterized using ICP-OES, HSM, gravimetric analysis, SEM/EDX, and XRD, and the carbon dioxide flux density was quantified using a high-temperature membrane permeation setup. The carbon dioxide permeability slightly increases with the addition of iron in the FSDC membranes compared to the SDC membranes mainly due to the reported scavenging effect of iron with the siliceous impurities, with an additional potential contribution of an increased crystallite size due to viscous flow sintering. The increased permeability of the FSDC system and the proper microstructure control by MgO can be further extended to optimize carbon dioxide permeability in this membrane system.</jats:p>