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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Przekop, Robert
Adam Mickiewicz University in Poznań
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (35/35 displayed)
- 2024Nanocomposites Based on Thermoplastic Acrylic Resin with the Addition of Chemically Modified Multi-Walled Carbon Nanotubescitations
- 2024Preparation and Characterization of Composites Based on ABS Modified with Polysiloxane Derivativescitations
- 2024The Influence of Surface Texture of Elements Made of PA6-Based Composites on Anti-Graffiti Effect of Paint Coating
- 2024Micro- and Nano-Pollutants from Tires and Car Brakes Generated in the Winter Season in the Poznan City Urban Environmentcitations
- 2024Enhancing the Thermal Resistance of UV-Curable Resin Using (3-Thiopropyl)polysilsesquioxanecitations
- 2024Application of L-FDM Technology to the Printing of Tablets That Release Active Substances—Preliminary Researchcitations
- 2024OH End-Capped Silicone as an Effective Nucleating Agent for Polylactide—A Robotizing Method for Evaluating the Mechanical Characteristics of PLA/Silicone Blendscitations
- 2023Liquid for Fused Deposition Modeling Technique (L-FDM)—A Revolution in Application Chemicals to 3D Printing Technology: Color and Elementscitations
- 2023Liquid to Fused Deposition Modeling (L-FDM)—A Revolution in Application Chemicals to 3D Printing Technology—Mechanical and Functional Propertiescitations
- 2023Beeswax as a natural alternative to synthetic waxes for fabrication of PLA/diatomaceous earth compositescitations
- 2023Robotization of Three-Point Bending Mechanical Tests Using PLA/TPU Blends as an Example in the 0–100% Rangecitations
- 2023Feldspar-Modified Methacrylic Composite for Fabrication of Prosthetic Teethcitations
- 2023Organosilicon Compounds in Hot-Melt Adhesive Technologiescitations
- 2023Polyamide 11 Composites Reinforced with Diatomite Biofiller—Mechanical, Rheological and Crystallization Propertiescitations
- 2022The Influence of Organofunctional Substituents of Spherosilicates on the Functional Properties of PLA/TiO2 Composites Used in 3D Printing (FDM/FFF)citations
- 2022Aspects and Principles of Material Connections in Restorative Dentistry—A Comprehensive Reviewcitations
- 2022Biocomposites Based on Polyamide 11/Diatoms with Different Sized Frustulescitations
- 2022New Ceramics Precursors Containing Si and Ge Atoms—Cubic Germasilsesquioxanes—Synthesis, Thermal Decomposition and Spectroscopic Analysiscitations
- 2022Where ppm Quantities of Silsesquioxanes Make a Difference—Silanes and Cage Siloxanes as TiO<inf>2</inf> Dispersants and Stabilizers for Pigmented Epoxy Resinscitations
- 2022Carbonate Lake Sediments in the Plastics Processing-Preliminary Polylactide Composite Case Study: Mechanical and Structural Propertiescitations
- 2022Metallic Strontium as a Precursor of the Al2O3/SrCO3 Xerogels Obtained by the One-Pot Sol–Gel Methodcitations
- 2022Influence of Diatomaceous Earth Particle Size on Mechanical Properties of PLA/Diatomaceous Earth Compositescitations
- 2022Novel Multifunctional Spherosilicate-Based Coupling Agents for Improved Bond Strength and Quality in Restorative Dentistrycitations
- 2021Sol-Gel Approach for Design of Pt/Al2O3-TiO2 System-Synthesis and Catalytic Testscitations
- 2021Methodological Aspects of Obtaining and Characterizing Composites Based on Biogenic Diatomaceous Silica and Epoxy Resinscitations
- 2021Phytotoxic effects of biosynthesized ZnO nanoparticles using Betonica officinalis extractcitations
- 2021A Wind Tunnel Experimental Study of Icing on NACA0012 Aircraft Airfoil with Silicon Compounds Modified Polyurethane Coatingscitations
- 2021A New Method of Diatomaceous Earth Fractionation—A Bio-Raw Material Source for Epoxy-Based Compositescitations
- 2021Metallic Calcium as a Precursor for Sol-Gel Synthesis of CaCO3-SiO2 and CaO-SiO2 Systemscitations
- 2021Why POSS-Type Compounds Should Be Considered Nanomodifiers, Not Nanofillers—A Polypropylene Blends Case Studycitations
- 2020Highly bulky spherosilicates as functional additives for polyethylene processing--Influence on mechanical and thermal propertiescitations
- 2019The influence of surface physicochemistry of solid fillers on dispersion in polyurea systems
- 2018One-pot synthesis of Al2O3-La2O2CO3 systems obtained from the metallic precursor by the sol-gel methodcitations
- 2018A new method of one-pot synthesis of efficient Au/SnO <inf>2</inf> electrocatalysts for fuel cells
- 2018New method for the synthesis of Al2O3–CaO and Al2O3–CaO–CaCO3 systems from a metallic precursor by the sol–gel routecitations
Places of action
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article
Enhancing the Thermal Resistance of UV-Curable Resin Using (3-Thiopropyl)polysilsesquioxane
Abstract
<jats:p>This study delineates a methodology for the preparation of new composites based on a photocurable urethane-acrylate resin, which has been modified with (3-thiopropyl)polysilsesquioxane (SSQ-SH). The organosilicon compound combines fully enclosed cage structures and incompletely condensed silanols (a mixture of random structures) obtained through the hydrolytic condensation of (3-mercaptopropyl)trimethoxysilane. This process involves a thiol-ene “click” reaction between SSQ-SH and a commercially available resin (Ebecryl 1271®) in the presence of the photoinitiator DMPA, resulting in composites with significantly changed thermal properties. Various tests were conducted, including thermogravimetric analysis (TGA), Fourier transmittance infrared spectroscopy (FT-IR), differential scanning calorimetry (Photo-DSC), and photoreological measurement mechanical property, and water contact angle (WCA) tests. The modification of resin with SSQ-SH increased the temperature of 1% and 5% mass loss compared to the reference (for 50 wt% SSQ-SH, T5% was 310.8 °C, an increase of 20.4 °C). A composition containing 50 wt% of SSQ-SH crosslinked faster than the reference resin, a phenomenon confirmed by photorheological tests. This research highlights the potential of new composite materials in coating applications across diverse industries. The modification of resin with SSQ-SH not only enhances thermal properties but also introduces a host of functional improvements, thereby elevating the performance of the resulting coatings.</jats:p>