| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Dudziec, Beata
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (14/14 displayed)
- 2024Preparation of T8 and double-decker silsesquioxane-based Janus-type molecules: molecular modeling and DFT insights
- 2024Crystallization behavior and thermal properties of octa-phenyl-substituted silsesquioxane-modified polylactide (PLA)citations
- 2023Metallodendrimers Unveiled: Investigating the Formation and Features of Double-Decker Silsesquioxane-Based Silylferrocene Dendrimerscitations
- 2022Slick Synthetic Approach to Various Fluoroalkyl Silsesquioxanes—Assessment of their Dielectric Propertiescitations
- 2019Synthetic routes to silsesquioxane-based systems as photoactive materials and their precursorscitations
- 2018Multi-alkenylsilsesquioxanes as comonomers and active species modifiers of metallocene catalyst in copolymerization with ethylenecitations
- 2018Interfacial interactions in PTT–PTMO/polyhedral oligomeric silsesquioxane (POSS) nanocomposites and their impact on mechanical, thermal, and dielectric propertiescitations
- 2017Copolymers of ethylene with monoalkenyl- and monoalkenyl(siloxy)silsesquioxane (POSS) comonomers – Synthesis and characterizationcitations
- 2017Evaluation of thermomechanical properties of epoxy–basalt fibre composites modified with zeolite and silsesquioxanecitations
- 2016Morphology, mechanical properties and processability of poly(ethylene terephthalate) modified by polyhedral oligomeric silsesquioxanes
- 2015Morphology and phase separation in PTT-block-PTMO nanocomposites containing POSS particlescitations
- 2014Influence of a sorbitol-based nucleating agent modified with silsesquioxanes on the non-isothermal crystallization of isotactic polypropylenecitations
- 2014Thermal Stability and Flammability of Polypropylene-Silsesquioxane Nanocompositescitations
- 2013Processing properties of thermoplastic polymers modified by polyhedral oligomeric silsesquioxanes (POSS)citations
Places of action
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article
Slick Synthetic Approach to Various Fluoroalkyl Silsesquioxanes—Assessment of their Dielectric Properties
Abstract
<jats:p>We present a smart and efficient methodology for the synthesis of a variety of fluorinated silsesquioxanes (SQs) with diverse Si-O-Si core architecture. The protocol is based on an easy-to-handle and selective hydrosilylation reaction. An investigation on the placement of the reactive Si-HC=CH2 vs. Si-H in the silsesquioxane, as well as silane vs. olefin structure, respectively, on the progress and selectivity of the hydrosilylation process, was studied. Two alternative synthetic pathways for obtaining a variety of fluorine-functionalized silsesquioxanes were developed. As a result, a series of mono- and octa- T8 SQs, tri- ‘open-cage’ T7 SQs, in addition to di- and tetrafunctionalized double-decker silsesquioxane (DDSQ) derivatives, were obtained selectively with high yields. All products were characterized by spectroscopic (NMR, FTIR) techniques. Selected samples were subjected to the measurements revealing their dielectric permittivity in a wide range of temperatures (from −100 °C to 100 °C) and electric field frequencies (100–106 Hz).</jats:p>