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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Bernik, Slavko
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Topics
Publications (17/17 displayed)
- 2023The influence of spark plasma sintering temperature on the properties of Sb-doped barium stannate ceramics
- 2023Thermoelectric properties of pseudobrookite-based ceramics prepared from natural Fe-Ti-rich heavy mineral sand concentratecitations
- 2023Thermoelectric properties of pseudobrookite-based ceramics prepared from natural Fe-Ti-rich heavy mineral sand concentratecitations
- 2023Thermoelectric Cu doped sodium cobaltite – structural, magnetic and mechanical properties
- 2022Effect of Cu dopping on microstructural, thermoelectric and mechanical properties of NaCoCuO4 ceramics
- 2022Microstructural, Thermoelectric and Mechanical Properties of Cu Substituted NaCo2O4citations
- 2022Microstructural, Thermoelectric and Mechanical Properties of Cu Substituted NaCo2O4citations
- 2022Effect of the sintering technique on the properties of Sb-doped BaSnO3 ceramics
- 2020Improvement in the thermoelectric properties of porous networked Al-doped ZnO nanostructured materials synthesized via an alternative interfacial reaction and low-pressure SPS processingcitations
- 2019Structural, microstructural and electrical properties of Sb-doped BaSnO3 ceramics
- 2019Spark plasma sintering of conductive Sb-doped BaSnO3
- 2018Improvement of density and influence of Sb doping on structural properties of perovskite BaSnO3
- 2018Phonon Scattering and Electron Doping by 2D Structural Defects in In/ZnOcitations
- 2017Structural features and thermoelectric properties of Al-doped (ZnO)(5)In2O3 homologous phasescitations
- 2017TEM study of basal-plane inversion boundaries in Sn‐Doped ZnO
- 2017Enhancement of thermoelectric properties induced by Cu substitution in NaCo2O4
- 2016THERMOELECTRIC PROPERTIES OF NaCo2–xCuxO4 (x = 0, 0.01, 0.03, 0.05) CERAMIC
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article
Microstructural, Thermoelectric and Mechanical Properties of Cu Substituted NaCo2O4
Abstract
<jats:p>Polycrystalline samples of NaCo2−xCuxO4 (x = 0, 0.01, 0.03, 0.05) were obtained from powder precursors synthesized by a mechanochemically assisted solid-state reaction method (MASSR) and a citric acid complex method (CAC). Ceramic samples were prepared by pressing into disc-shaped pellets and subsequently sintering at 880 °C in an argon atmosphere. Effects of low concentrations of Cu doping and the above-mentioned synthesis procedures on the thermoelectric and mechanical properties were observed. The electrical resistivity (ρ), the thermal conductivity (κ) and the Seebeck coefficient (S) were measured simultaneously in the temperature gradient (ΔT) between the hot and cold side of the sample, and the figure of merit (ZT) was subsequently calculated. The ZT of the CAC samples was higher compared with the MASSR samples. The highest ZT value of 0.061 at ΔT = 473 K was obtained for the sample with 5 mol% of Cu prepared by the CAC method. The CAC samples showed better mechanical properties compared to the MASSR samples due to the higher hardness of the CAC samples which is a consequence of homogeneous microstructure and higher density obtained during sintering of these samples. The results confirmed that, besides the concentration of Cu, the synthesis procedure considerably affected the thermoelectric and mechanical properties of NaCo2O4 (NCO) ceramics.</jats:p>