• Munteanu, Corneliu
• Lohan, Nicoleta Monica
• Zegan, Georgeta
• Cimpoeșu, Nicanor
• Ioanid, Nicoleta
• Ioniță, Iulian
• Roman, Ana-Maria
• Cernei, Eduard Radu
• Cimpoeșu, Ramona
• Geantă, Victor

Abstract

<jats:p>Special materials are required in many applications to fulfill specific medical or industrial necessities. Biodegradable metallic materials present many attractive properties, especially mechanical ones correlated with good biocompatibility with vivant bodies. A biodegradable iron-based material was realized through electric arc-melting and induction furnace homogenization. The new chemical composition obtained presented a special property named SME (shape memory effect) based on the martensite transformation. Preliminary results about this special biodegradable material with a new chemical composition were realized for the chemical composition and structural and thermal characterization. Corrosion resistance was evaluated in Ringer’s solution through immersion tests for 1, 3, and 7 days, the solution pH was measured in time for 3 days with values for each minute, and electro-corrosion was measured using a potentiostat and a three electrode cell. The mass loss of the samples during immersion and electro-corrosion was evaluated and the surface condition was studied by scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS). SME was highlighted with differential scanning calorimetry (DSC). The results confirm the possibility of a memory effect of the materials in the wrought case and a generalized corrosion (Tafel and cyclic potentiometry and EIS) with the formation of iron oxides and a corrosion rate favorable for applications that require a longer implantation period.</jats:p>

Topics

• surface
• corrosion
• scanning electron microscopy
• chemical composition
• differential scanning calorimetry
• iron
• electrochemical-induced impedance spectroscopy
• Energy-dispersive X-ray spectroscopy
• homogenization
• biocompatibility
• potentiometry