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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Brząkalski, Dariusz
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (14/14 displayed)
- 2024Nanocomposites Based on Thermoplastic Acrylic Resin with the Addition of Chemically Modified Multi-Walled Carbon Nanotubescitations
- 2023Beeswax as a natural alternative to synthetic waxes for fabrication of PLA/diatomaceous earth compositescitations
- 2023Feldspar-Modified Methacrylic Composite for Fabrication of Prosthetic Teethcitations
- 2023Organosilicon Compounds in Hot-Melt Adhesive Technologiescitations
- 2023Polyamide 11 Composites Reinforced with Diatomite Biofiller—Mechanical, Rheological and Crystallization Propertiescitations
- 2022Aspects and Principles of Material Connections in Restorative Dentistry—A Comprehensive Reviewcitations
- 2022Where ppm Quantities of Silsesquioxanes Make a Difference—Silanes and Cage Siloxanes as TiO<inf>2</inf> Dispersants and Stabilizers for Pigmented Epoxy Resinscitations
- 2022Influence of Diatomaceous Earth Particle Size on Mechanical Properties of PLA/Diatomaceous Earth Compositescitations
- 2022Novel Multifunctional Spherosilicate-Based Coupling Agents for Improved Bond Strength and Quality in Restorative Dentistrycitations
- 2021Methodological Aspects of Obtaining and Characterizing Composites Based on Biogenic Diatomaceous Silica and Epoxy Resinscitations
- 2021A New Method of Diatomaceous Earth Fractionation—A Bio-Raw Material Source for Epoxy-Based Compositescitations
- 2021Why POSS-Type Compounds Should Be Considered Nanomodifiers, Not Nanofillers—A Polypropylene Blends Case Studycitations
- 2020Highly bulky spherosilicates as functional additives for polyethylene processing--Influence on mechanical and thermal propertiescitations
- 2019The influence of surface physicochemistry of solid fillers on dispersion in polyurea systems
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article
Where ppm Quantities of Silsesquioxanes Make a Difference—Silanes and Cage Siloxanes as TiO<inf>2</inf> Dispersants and Stabilizers for Pigmented Epoxy Resins
Abstract
<p>In this work, silsesquioxane and spherosilicate compounds were assessed as novel organosilicon coupling agents for surface modification of TiO<sub>2</sub> in a green process, and compared with their conventional silane counterparts. The surface-treated TiO<sub>2</sub> particles were then applied in preparation of epoxy (EP) composites and the aspects of pigment dispersion, suspension stability, hiding power, as well as the composite mechanical and thermal properties were discussed. The studied compounds loading was between 0.005–0.015% (50–150 ppm) in respect to the bulk composite mass and resulted in increase of suspension stability and hiding power by over an order of magnitude. It was found that these compounds may be an effective alternative for silane coupling agents, yet due to their low cost and simplicity of production and manipulation, silanes and siloxanes are still the most straight-forward options available. Nonetheless, the obtained findings might encourage tuning of silsesquioxane compounds structure and probably process itself if implementation of these novel organosilicon compounds as surface treatment agents is sought for special applications, e.g., high performance coating systems.</p>