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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Gressier, Marie
Université Toulouse III - Paul Sabatier
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (13/13 displayed)
- 2022Fabrication of a pH microsensor for local pH measurement during chromium electrodeposition from a trivalent chromium-based electrolytecitations
- 2022Fabrication of a pH microsensor for local pH measurement during chromium electrodeposition from a trivalent chromium-based electrolytecitations
- 2021Influence of Hybrid Sol-Gel Crosslinker on Self-Healing Properties for Multifunctional Coatingscitations
- 2020Near-Infrared Luminescence from Visible-Light-Sensitized Ruthenium(II)‑Neodymium(III) Heterobimetallic Bridged Complexes Containing Alkoxy(silyl) Functional Groupscitations
- 2018Innovative Formulation Combining Al, Zr and Si Precursors to Obtain Anticorrosion Hybrid Sol-Gel Coatingcitations
- 2016New architectured hybrid sol-gel coatings for wear and corrosion protection of low-carbon steelcitations
- 2016Bifunctional magnetic luminescent particles based on iron oxide nanoparticles grafted with a europium silylated bypiridine tris(β-diketonate) complexcitations
- 2016Luminescent multifunctional hybrids obtained by grafting of ruthenium complexes on mesoporous silicacitations
- 2013Protection against corrosion of magnesium alloys with both conversion layer and sol–gel coatingcitations
- 2012Improvement of barrier properties of a hybrid sol-gel coating by incorporation of synthetic talc-like phyllosilicates for corrosion protection of a carbon steelcitations
- 2009High rate capability pure Sn-based nano-architectured electrode assembly for rechargeable lithium batteriescitations
- 2009High rate capability pure Sn-based nano-architectured electrode assembly for rechargeable lithium batteriescitations
- 2007Silica-Based Nanohybrids Containing Dipyridine, Urethan, or Urea Derivativescitations
Places of action
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article
Influence of Hybrid Sol-Gel Crosslinker on Self-Healing Properties for Multifunctional Coatings
Abstract
Self-healing polymers are a new class of material that has recently received a lot of attention because of the lifespan improvement it could bring to multiple applications. One of the major challenges is to obtain multifunctional materials which can self-heal and exhibit other interesting properties such as protection against corrosion. In this paper, the effect of the incorporation of an aminosilane on the properties of a self-healing organic polymer containing disulfide bond is studied on films and coatings for aluminium AA2024-T3 using simple one step in situ synthesis. Hybrid coatings with enhanced anticorrosion properties measured by EIS were obtained thanks to the formation of a protective oxide interface layer, while exhibiting wound closure after exposition at 75 °C. The thermal, mechanical and rheological properties of the films with different aminosilane amounts were characterized in order to understand the influence of the slight presence of the inorganic network. Stiffer and reprocessable hybrid films were obtained, capable to recover their mechanical properties after healing. The nanocomposite structure, confirmed by TEM, had a positive effect on the self-healing and stress relaxation properties. These results highlight the potential of sol-gel chemistry to obtain efficient anticorrosion and self-healing coatings.