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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Pavlyuk, Volodymyr
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (10/10 displayed)
- 2024Intermetallic Materials for High-Capacity Hydrogen Storage Systems
- 2023MAl4Ir2 (M = Ca, Sr, Eu): superstructures of the KAu4In2 typecitations
- 2022MAl4Ir2 (M = Ca, Sr, Eu) : superstructures of the KAu4In2 type
- 2021Electrochemical hydrogenation, lithiation and sodiation of the GdFe2–xMx and GdMn2–xMx intermetallics
- 2021Enhancement of Y5−xPrxSb3−yMy (M = Sn, Pb) Electrodes for Lithium- and Sodium-Ion Batteries by Structure Disordering and CNTs Additivescitations
- 2019Li20Mg6Cu13Al42: a new ordered quaternary superstructure to the icosahedral T-Mg32(Zn,Al)49 phase with fullerene-like Al60 clustercitations
- 2019La3Ni4Al2: a new layered aluminidecitations
- 2017LiBC<sub>3</sub>: a new borocarbide based on graphene and heterographene networkscitations
- 2014High hydrogen content super-lightweight intermetallics from the Li–Mg–Si systemcitations
- 2012Terbium (lithium zinc) distannide, TbLi1–xZnxSn2 (x = 0.2)citations
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article
Enhancement of Y5−xPrxSb3−yMy (M = Sn, Pb) Electrodes for Lithium- and Sodium-Ion Batteries by Structure Disordering and CNTs Additives
Abstract
<jats:p>The maximally disordered (MD) phases with the general formula Y5−xPrxSb3−yMy (M = Sn, Pb) are formed with partial substitution of Y by Pr and Sb by Sn or Pb in the binary Y5Sb3 compound. During the electrochemical lithiation and sodiation, the formation of Y5-xPrxSb3-yMyLiz and Y5−xPrxSb3−yMyNaz maximally disordered–high entropy intermetallic phases (MD-HEIP), as the result of insertion of Li/Na into octahedral voids, were observed. Carbon nanotubes (CNT) are an effective additive to improve the cycle stability of the Y5−xPrxSb3−yMy (M = Sn, Pb) anodes for lithium-ion (LIBs) and sodium-ion batteries (SIBs). Modification of Y5−xPrxSb3−ySny alloys by carbon nanotubes allowed us to significantly increase the discharge capacity of both types of batteries, which reaches 280 mAh · g−1 (for LIBs) and 160 mAh · g−1 (for SIBs), respectively. For Y5−xPrxSb3−yPby alloys in which antimony is replaced by lead, these capacities are slightly smaller and are 270 mAh · g−1 (for LIBs) and 155 mAh · g−1 (for SIBs), respectively. Results show that structure disordering and CNT additives could increase the electrode capacities up to 30% for LIBs and up to 25% for SIBs.</jats:p>