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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Piech, Robert
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (9/9 displayed)
- 2024Poly(3,4-ethylenedioxythiophene) and Poly(3-octylthiophene-2,5-diyl) Molecules as Composite Transducers in Potentiometric Sensors—Synthesis and Application
- 2024Highly Sensitive Trimetazidine Determination Using Composite Yttria-Stabilized Zirconia Doped with Titanium Oxide–Carbon Black Biosensorcitations
- 2023Hierarchical carbon nanofibers/carbon nanotubes/NiCo nanocomposites as novel highly effective counter electrode for dye-sensitized solar cells: A structure-electrocatalytic activity relationship studycitations
- 2022Hydrous Cerium Dioxide-Based Materials as Solid-Contact Layers in Potassium-Selective Electrodescitations
- 2021Potentiometric Sensor with High Capacity Composite Composed of Ruthenium Dioxide and Poly(3,4-ethylenedioxythiophene) Polystyrene Sulfonatecitations
- 2021Graphene Flakes Decorated with Dispersed Gold Nanoparticles as Nanomaterial Layer for ISEscitations
- 2021High Capacity Nanocomposite Layers Based on Nanoparticles of Carbon Materials and Ruthenium Dioxide for Potassium Sensitive Electrodecitations
- 2019Ruthenium dioxide nanoparticles as a high-capacity transducer in solid-contact polymer membrane-based pH-selective electrodescitations
- 2017Voltammetric determination of trace elements (Cu, Pb, Zn) in peloid-based pharmaceuticals
Places of action
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article
High Capacity Nanocomposite Layers Based on Nanoparticles of Carbon Materials and Ruthenium Dioxide for Potassium Sensitive Electrode
Abstract
<jats:p>This work presents the new concept of designing ion-selective electrodes based on the use of new composite materials consisting of carbon nanomaterials and ruthenium dioxide. Using two different materials varying in microstructure and properties, we could obtain one material for the mediation layer that adopted features coming of both components. Ruthenium dioxide characterized by high electrical capacity and mixed electronic-ionic transduction and nano-metric carbon materials were reportedly proved to improve the properties of ion-selective electrodes. Initially, only the materials and then the final electrodes were tested in the scope of the presented work, using scanning and transmission electron microscope, contact angle microscope, and various electrochemical techniques, including electrochemical impedance spectroscopy and chronopotentiometry. The obtained results confirmed beneficial influence of the designed nanocomposites on the ion-selective electrodes’ properties. Nanosized structure, high capacity (characterized by the electrical capacitance value from approximately 5.5 mF for GR + RuO2 and CB + RuO2, up to 14 mF for NT + RuO2) and low hydrophilicity (represented by the contact angle from 60° for GR+RuO2, 80° for CB+RuO2, and up to 100° for NT + RuO2) of the mediation layer materials, allowed us to obtain water layer-free potassium-selective electrodes, characterized by rapid and stable potentiometric response in a wide range of concentrations-from 10−1 to 10−6 M K+.</jats:p>