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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Ros, Josep
Universitat Autònoma de Barcelona
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (16/16 displayed)
- 2021Preparation and characterization of nanoparticle-doped polymer inclusion membranescitations
- 2021Preparation and Characterization of Nanoparticle-Doped Polymer Inclusion Membranes: Application to the Removal of Arsenate and Phosphate from Waterscitations
- 2018Tailoring the Synthesis of LnF3 (Ln = La–Lu and Y) Nanocrystals via Mechanistic Study of the Coprecipitation Method
- 2018Epitaxial YBa2Cu3O7−x nanocomposite films and coated conductors from BaMO3 (M = Zr, Hf) colloidal solutions
- 2016Unique nanostructural features in Fe, Mndoped YBCO thin filmscitations
- 2016Ultra- fast microwave-assisted reverse microemulsion synthesis of Fe3O4@SiO2 core–shell nanoparticles as a highly recyclable silver nanoparticle catalytic platform in the reduction of 4- nitroanilinecitations
- 2013Study of new metallomacrocyclic Pd(ii) complexes based on hybrid pyrazole sulfoxide/sulfone ligands and their contribution to supramolecular networkscitations
- 2011Variable behaviour of flexible N,O-mixed pyrazole ligand towards Zn(ii), Cd(ii) and Hg(ii) ions. Synthesis, crystal structure and fluorescent propertiescitations
- 2010Synthesis, X-ray crystal structure and NMR characterisation of mononuclear Pd(II) and Pt(II) complexes of didentate ligands with NN′-donor setcitations
- 2010Synthesis and characterization of new N-alkylamino-3,5-diphenylpyrazole ligands and reactivity toward PdII and PtII. Study of the cis-trans isomerizationcitations
- 2009Reactivity of [PdCl(bdtp)](BF4) with monodentate neutral and anionic ligands. Structure of [Pd(bdtp)(PPh3)](BF4)2 (bdtp = 1,5-bis(3,5-dimethyl-1-pyrazolyl)-3-thiapentane)citations
- 2008Synthesis, characterization and X-ray crystal structure determination of cyclopalladated [Csp2,N,N′]-, zwitterionic and chelated compounds in the reaction of 3,5-diphenyl-N-alkylaminopyrazole derived ligands with Pd(II)citations
- 2007Preparation and structural characterisation of a Cd(II) complex with unusual geometrycitations
- 2006Synthesis of new palladium(II) compounds with several bidentate nitrogen-donor ligands: Structural analyses by 1H and 13C{1H} NMR spectroscopy and crystal structurescitations
- 2003Synthesis, X-ray crystal structure, and NMR characterisation of thiolate-bridged dinuclear Ni(II), Pd(II) and Pt(II) complexes of didentate ligands with NS-donor setcitations
- 2003Synthesis, characterisation, and X-ray crystal structure of new Ni II, PdII, and PtII complexes of tridentate pyrazole-based ligands with an NOS-donor setcitations
Places of action
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article
Preparation and characterization of nanoparticle-doped polymer inclusion membranes
Abstract
<p>Nanoparticle-doped polymer inclusion membranes (NP-PIMs) have been prepared and characterized as new materials for the removal of arsenate and phosphate from waters. PIMs are made of a polymer, cellulose triacetate (CTA), and an extractant, which interacts with the compound of interest. We have used the ionic liquid (IL) trioctylmethylammonium chloride (Aliquat 336) as the extractant and have investigated how the addition of nanoparticles can modify membrane prop-erties. To this end, inorganic nanoparticles, such as ferrite (Fe3O4), SiO2 and TiO2, and multiwalled carbon nanotubes (MWCNTs), were blended with the polymer/extractant mixture. Scanning elec-tron microscopy (SEM), infrared spectroscopy (FT-IR), and contact angle measurements have been used to characterize the material. Moreover, PIM stability was checked by measuring the mass loss during the experiments. Since Aliquat 336 acts as an anion exchanger, the NP-PIMs have been ex-plored in two different applications: (i) as sorbent materials for the extraction of arsenate and phosphate anions; (ii) as an organic phase for the separation of arsenate and phosphate in a three-phase system. The presence of oleate-coated ferrite NP in the PIM formulation represents an improvement in the efficiency of NP-PIMs used as sorbents; nevertheless, a decrease in the transport efficiency for arsenate but not for phosphate was obtained. The ease with which the NP-PIMs are prepared suggests good potential for future applications in the treatment of polluted water. Future work will address three main aspects: firstly, the implementation of the Fe3O4-PIMs for the removal of As(V) in real water containing complex matrices; secondly, the study of phosphate recovery with other cell designs that allow large volumes of contaminated water to be treated; and thirdly, the investigation of the role of MWCNTs in PIM stability.</p>