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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Rahman, Mohammed M.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (10/10 displayed)
- 2023Two‐dimensional MXenes as Emerging Materials: A Comprehensive Reviewcitations
- 2023Recent Advances of Transition Metal Dichalcogenides‐Based Materials for Energy Storage Devices, in View of Monovalent to Divalent Ionscitations
- 2023Bimetallic CuO−ZnO Hybrid Nanocomposite Materials for Efficient Remediation of Environmental Pollutantscitations
- 2023Utilizing Nanostructured Materials for Hydrogen Generation, Storage, and Diverse Applicationscitations
- 2022Synthesis, Characterization and Bio-Potential Activities of Co(II) and Ni(II) Complexes with O and N Donor Mixed Ligandscitations
- 2022Efficient Detection of 2,6-Dinitrophenol with Silver Nanoparticle-Decorated Chitosan/SrSnO3 Nanocomposites by Differential Pulse Voltammetrycitations
- 2022Recent advances in hydrogen production using MXenes-based metal sulfide photocatalystscitations
- 2022Sensitive Electrochemical Detection of 4-Nitrophenol with PEDOT:PSS Modified Pt NPs-Embedded PPy-CB@ZnO Nanocompositescitations
- 2020A New Cr3+ Electrochemical Sensor Based on ATNA/Nafion/Glassy Carbon Electrodecitations
- 2019Semiconductor α‐Fe2O3 Hematite Fabricated Electrode for Sensitive Detection of Phenolic Pollutantscitations
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article
A New Cr3+ Electrochemical Sensor Based on ATNA/Nafion/Glassy Carbon Electrode
Abstract
<jats:p>A new electrochemical sensor of metal cation in an aqueous solution based on homobifunctional tridentate disulfide Schiff base and named 1,1′-(-((disulfanediylbis(2,1-phenylene))bis(azaneylylidene))bis(methaneylylidene))bis(naphthalene-2-ol) (ATNA) was easily obtained quantitatively from the condensation reaction of 2-hydroxy-1-naphthaldehyde and 2-aminothiophenol, and then fully characterized by spectroscopic techniques for structure elucidation. The molecular structure of ATNA was also confirmed by a single-crystal X-ray diffraction study to reveal a new conformation in which the molecule was stabilized by the O–H…N type intramolecular hydrogen bonding interactions in both moieties. The ATNA was used as a selective electrochemical sensor for the detection of chromium ion (Cr3+). A thin film of ATNA was coated on to the flat surface of glassy carbon electrode (GCE) followed by 5 % ethanolic Nafion in order to make the modified GCE (ATNA/Nafion/GCE) as an efficient and sensitive electrochemical sensor. It was found to be very effective and selective against Cr3+ cations in the company of other intrusive heavy metal cations such as Al3+, Ce3+, Co2+, Cu2+, Ga3+, Hg2+, Mn2+, Pb2+, and Y3+. The detection limit at 3 S/N was found to be 0.013 nM for Cr3+ ions within the linear dynamic range (LDR) (0.1 nM–10.0 mM) of Cr3+ ions with r2 = 0.9579. Moreover; this work instigates a new methodology for developing the sensitive as well as selective electrochemical toxic cationic sensors in the field of environmental and health care.</jats:p>