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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Szpikowska-Sroka, Barbara
University of Silesia
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (6/6 displayed)
- 2022Luminescence of SiO2-BaF2:Tb3+, Eu3+ nano-glass-ceramics made from sol-gel method at low temperaturecitations
- 2021Structural and photoluminescence investigations of Tb3+/Eu3+ codoped silicate sol-gel glass-ceramics containing CaF2 nanocrystalscitations
- 2020Energy transfer study on Tb3+/Eu3+ Co-activated sol-gel glass-ceramic materials containing MF3 (M = Y, La) nanocrystals for NUV optoelectronic devicescitations
- 2019Fabrication of fluoride nanocrystals and their spectroscopic properties
- 2019Reddish-Orange Luminescence from BaF2:Eu3+ Fluoride Nanocrystals Dispersed in Sol-Gel Materialscitations
- 2019Sol-Gel Glass-Ceramic Materials Containing CaF2:Eu3+ Fluoride Nanocrystals for Reddish-Orange Photoluminescence Applicationscitations
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article
Energy transfer study on Tb3+/Eu3+ Co-activated sol-gel glass-ceramic materials containing MF3 (M = Y, La) nanocrystals for NUV optoelectronic devices
Abstract
In the present work, the Tb3+/Eu3+ co-activated sol-gel glass-ceramic materials (GCs) containing MF3 (M = Y, La) nanocrystals were fabricated during controlled heat-treatment of silicate xerogels at 350 C. The studies of Tb3+ ! Eu3+ energy transfer process (ET) were performed by excitation and emission spectra along with luminescence decay analysis. The co-activated xerogels and GCs exhibit multicolor emission originated from 4fn–4fn optical transitions of Tb3+ (5D4 !7FJ, J = 6–3) as well as Eu3+ ions (5D0 ! 7FJ, J = 0–4). Based on recorded decay curves, it was found that there is a significant prolongation in luminescence lifetimes of the 5D4 (Tb3+) and the 5D0 (Eu3+) levels after the controlled heat-treatment of xerogels. Moreover, for both types of prepared GCs, an increase in ET e ciency was also observed (from ET 16% for xerogels up to ET = 37.3% for SiO2-YF3 GCs and ET = 60.8% for SiO2-LaF3 GCs). The changes in photoluminescence behavior of rare-earth (RE3+) dopants clearly evidenced their partial segregation inside low-phonon energy fluoride environment. The obtained results suggest that prepared SiO2-MF3:Tb3+, Eu3+ GC materials could be considered for use as optical elements in RGB-lighting optoelectronic devices operating under near-ultraviolet (NUV) excitation.