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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Kościelniak, Barbara
Rzeszów University of Technology
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (8/8 displayed)
- 2024Microstructure and Corrosion Resistance of 7075 Aluminium Alloy Composite Material Obtained from Chips in the High-Energy Ball Milling Process
- 2024The Structure of Boride Diffusion Coatings Produced on Selected Grades of Structural Steelscitations
- 2021The Duplex Coating Formation Using Plasma Nitriding and CrN PVD Deposition on X39CrMo17-1 Stainless Steelcitations
- 2021The Isothermal Oxidation of MCrAlY Protective Coatingscitations
- 2021The Influence of Process Parameters on Structure and Phase Composition of Boride Coatings Obtained on X39CrMo17-1 Stainless Steelcitations
- 2020Pentavalent Vanadium Species as Potential Corrosion Inhibitors of Al2Cu Intermetallic Phase in the Sulfuric(VI) Acid Solutionscitations
- 2020Influence of Crystallographic Orientation on Creep Resistance of Single-Crystal Superalloycitations
- 2019The Effect of Withdrawal Rate on Crystal Structure Perfection, Microstructure and Creep Resistance of Single Crystal Castings Made of CMSX-4 Nickel-Based Superalloycitations
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article
Pentavalent Vanadium Species as Potential Corrosion Inhibitors of Al2Cu Intermetallic Phase in the Sulfuric(VI) Acid Solutions
Abstract
<jats:p>The objective of this work was to test vanadium isopolyoxoanions as potential corrosion inhibitors of the intermetallic phase Al2Cu in sulfuric acid solutions at pH = 1.3 and 2.5. The intermetallic was melted in an electric arc furnace. Its phase composition was confirmed using X-ray diffraction, light microscopy, and differential scanning calorimetry. Then Al2Cu corrosion kinetics was studied. Chemical composition of the solution after corrosion was determined using inductively coupled plasma-optical emission spectroscopy. The surface of corroded specimens was analyzed using scanning electron microscopy and X-ray photoelectron spectroscopy. Subsequent electrochemical studies involved determination of open-circuit potential, electrochemical impedance spectra, and polarization curves. It was found that the Al2Cu phase corrodes selectively and vanadium isopolyoxoanions increase this process both at pH = 1.3 and 2.5 with two exceptions. Corrosion inhibition was observed for 100 and 200 mM of Na3VO4 at pH 1.3, with inhibition efficiency 78% and 62% respectively, due to precipitation of V2O5.</jats:p>