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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Schubert, Dirk W.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (20/20 displayed)
- 2025Ti3C2Tx‐UHMWPE Nanocomposites—Towards an Enhanced Wear‐Resistance of Biomedical Implantscitations
- 2024Chemical Synthesis of Atactic Poly-3-hydroxybutyrate (a-P3HB) by Self-Polycondensation: Catalyst Screening and Characterizationcitations
- 2024Genipin-Cross-Linked Silk Fibroin/Alginate Dialdehyde Hydrogel with Tunable Gelation Kinetics, Degradability, and Mechanical Properties: A Potential Candidate for Tissue Regenerationcitations
- 2023Progress on Electrospun Composite Fibers Incorporating Bioactive Glass: An Overviewcitations
- 20233D-Printed Multifunctional Hydrogels with Phytotherapeutic Properties: Development of Essential Oil-Incorporated ALG-XAN Hydrogels for Wound Healing Applicationscitations
- 2023Pre‐Crosslinking with Hydrogel Microparticles Enhances the Printability of Alginate‐Based Inkscitations
- 2023Model to Predict Polymer Fibre Diameter during Melt Spinningcitations
- 2022Stress relaxation amplitude of hydrogels determines migration, proliferation, and morphology of cells in 3-D culturecitations
- 2022Improved 3D Printing and Cell Biology Characterization of Inorganic-Filler Containing Alginate-Based Composites for Bone Regeneration: Particle Shape and Effective Surface Area Are the Dominant Factors for Printing Performancecitations
- 2022Hierarchical Slice Patterns Inhibit Crack Propagation in Brittle Sheetscitations
- 2021Hemp Fiber Reinforced Red Mud/Fly Ash Geopolymer Composite Materials: Effect of Fiber Content on Mechanical Strengthcitations
- 2021An organic-inorganic hybrid scaffold with honeycomb-like structures enabled by one-step self-assembly-driven electrospinningcitations
- 2021Molecular changes induced in melanoma by cell culturing in 3D alginate hydrogelscitations
- 2021Revealing Electrical and Mechanical Performances of Highly Oriented Electrospun Conductive Nanofibers of Biopolymers with Tunable Diametercitations
- 2020Comparison of hydrogels for the development of well-defined 3d cancer models of breast cancer and melanomacitations
- 2020Preparation and Characterization of Electrospun Blend Fibrous Polyethylene Oxide:Polycaprolactone Scaffolds to Promote Cartilage Regenerationcitations
- 2020On the Determination of the Enthalpy of Fusion of α‐Crystalline Isotactic Polypropylene Using Differential Scanning Calorimetry, X‐Ray Diffraction, and Fourier‐Transform Infrared Spectroscopy: An Old Story Revisitedcitations
- 2020Cell-laden alginate dialdehyde–gelatin hydrogels formed in 3D printed sacrificial gelcitations
- 2019Polymer-Functionalised Nanograins of Mg-Doped Amorphous Calcium Carbonate via a Flow-Chemistry Approachcitations
- 2019Curcumin-Containing Orthopedic Implant Coatings Deposited on Poly-Ether-Ether-Ketone/Bioactive Glass/Hexagonal Boron Nitride Layers by Electrophoretic Depositioncitations
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article
Polymer-Functionalised Nanograins of Mg-Doped Amorphous Calcium Carbonate via a Flow-Chemistry Approach
Abstract
Calcareous biominerals typically feature a hybrid nanogranular structure consisting of calcium carbonate nanograins coated with organic matrices. This nanogranular organisation has a beneficial effect on the functionality of these bioceramics. In this feasibility study, we successfully employed a flow-chemistry approach to precipitate Mg-doped amorphous calcium carbonate particles functionalized by negatively charged polyelectrolytes—either polyacrylates (PAA) or polystyrene sulfonate (PSS). We demonstrate that the rate of Mg incorporation and, thus, the ratio of the Mg dopant to calcium in the precipitated amorphous calcium carbonate (ACC), is flow rate dependent. In the case of the PAA-functionalized Mg-doped ACC, we further observed a weak flow rate dependence concerning the hydration state of the precipitate, which we attribute to incorporated PAA acting as a water sorbent; a behaviour which is not present in experiments with PSS and without a polymer. Thus, polymer-dependent phenomena can affect flow-chemistry approaches, that is, in syntheses of functionally graded materials by layer-deposition processes.