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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Rozman, Kristina Zuzek
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Publications (3/3 displayed)
- 2020Limitations in grain boundary processing of the recycled HDDR Nd-Fe-B systemcitations
- 2020Image analysis data for the study of the reactivity of the phases in Nd-Fe-B magnets etched with HCl-saturated Cyphos IL 101citations
- 2019Coercivity increase of the recycled HDDR Nd-Fe-B powders doped with DyF3 and processed via Spark Plasma Sintering & the effect of thermal treatmentscitations
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article
Coercivity increase of the recycled HDDR Nd-Fe-B powders doped with DyF3 and processed via Spark Plasma Sintering & the effect of thermal treatments
Abstract
The magnetic properties of the recycled HDDR Nd-Fe-B powder doped with a low weight fraction of DyF3 nanoparticles were investigated. Spark plasma sintering (SPS) was used to consolidate the recycled Nd-Fe-B powder blends containing 1, 2 and 5 wt. % of DyF3 grounded powder. Different post SPS sintering thermal treatment conditions (600, 750 and 900 OC) for a varying amount of time were studied in view of optimizing the magnetic properties and developing characteristic core-shell microstructure in the HDDR powder. As received recycled HDDR powder has coercivity (HCi) of 830 kA/m and as optimally as SPS-ed magnets reach 1160 kA/m after the thermal treatment. With only 1 – 2 wt. % blended DyF3, the HCi peaked to 1407 kA/m with the thermal treatment at 750 OC for 1 hour. The obtained HCi values of the blend magnet is 41% higher than the starting recycled HDDR powder and 17.5% higher than the SPS-ed processed magnet annealed at 750 OC for 1 hour. Prolonging the thermal treatment time to 6 hours and temperature conditions above 900 OC was detrimental to the magnetic properties. About ~2 wt. % DyF3 dopant was suitable to develop a uniform core-shell microstructure in the HDDR Nd-Fe-B powder. The Nd-rich phase in the HDDR powder has a slightly different and fluorine rich composition i.e. Nd-O-F2 than in the one reported in sintered magnets (Nd-O-F). The composition of reaction zone-phases after the thermal treatment and Dy diffusion was DyF4, which is more abundant in 5 wt. % doped samples. Further doping above 2 wt. % DyF3 is ineffective in augmenting the coercivity of the recycled HDDR powder due to the decomposition of the shell structure and formation of non-ferromagnetic rare earth based complex intermetallic compounds. The DyF3 doping is a very effective single step route in a controlled coercivity improvement of the recycled HDDR Nd-Fe-B powder from the end of life magnetic products.