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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Wießner, Sven
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Topics
Publications (16/16 displayed)
- 2024Unlocking the Potential of Lignin: Towards a Sustainable Solution for Tire Rubber Compound Reinforcementcitations
- 2022Electrically conductive and piezoresistive polymer nanocomposites using multiwalled carbon nanotubes in a flexible copolyester: Spectroscopic, morphological, mechanical and electrical properties
- 2022Thermoelectric Performance of Polypropylene/Carbon Nanotube/Ionic Liquid Composites and Its Dependence on Electron Beam Irradiationcitations
- 2021First-Time Investigations on Cavitation in Rubber Parts Subjected to Constrained Tension Using In Situ Synchrotron X-Ray Microtomography (SRμCT)citations
- 2021Treasuring waste lignin as superior reinforcing filler in high cis-polybutadiene rubbercitations
- 2021Fundamentals and working mechanisms of artificial muscles with textile application in the loopcitations
- 2021A new strategy to improve viscoelasticity, crystallization and mechanical properties of polylactidecitations
- 2021Improved rheology, crystallization, and mechanical performance of PLA/mPCL blends prepared by electron-induced reactive processingcitations
- 2020Friction, abrasion and crack growth behavior of in-situ and ex-situ silica filled rubber compositescitations
- 2018Development and testing of controlled adaptive fiber-reinforced elastomer composites.citations
- 2018Development and testing of controlled adaptive fiber-reinforced elastomer compositescitations
- 2018Blending In Situ Polyurethane-Urea with Different Kinds of Rubber: Performance and Compatibility Aspectscitations
- 2017Strong Strain Sensing Performance of Natural Rubber Nanocompositescitations
- 2017Benefits of hybrid nano-filler networking between organically modified Montmorillonite and carbon nanotubes in natural rubber: Experiments and theoretical interpretations
- 2017Temperature-Dependent Reinforcement of Hydrophilic Rubber Using Ice Crystals
- 2006Effects of interface reactions in complatibilised ground tyre rubber polypropylene etastomeric alloyscitations
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article
Blending In Situ Polyurethane-Urea with Different Kinds of Rubber: Performance and Compatibility Aspects
Abstract
Specific physical and reactive compatibilization strategies are applied to enhance the interfacial adhesion and mechanical properties of heterogeneous polymer blends. Another pertinent challenge is the need of energy-intensive blending methods to blend high-tech polymers such as the blending of a pre-made hard polyurethane (-urea) with rubbers. We developed and investigated a reactive blending method to prepare the outstanding blends based on polyurethane-urea and rubbers at a low blending temperature and without any interfacial compatibilizing agent. In this study, the polyurethane-urea (PUU) was synthesized via the methylene diphenyl diisocyanate end-capped prepolymer and m-phenylene diamine based precursor route during blending at 100 °C with polar (carboxylated nitrile rubber (XNBR) and chloroprene rubber (CR)) and non-polar (natural rubber (NR), styrene butadiene rubber (sSBR), and ethylene propylene butadiene rubber (EPDM)) rubbers. We found that the in situ PUU reinforces the tensile response at low strain region and the dynamic-mechanical response up to 150 °C in the case of all used rubbers. Scanning electron microscopy reveals a stronger rubber/PUU interface, which promotes an effective stress transfer between the blend phases. Furthermore, energy filtered transmission electron microscopy (EFTEM) based elemental carbon map identifies an interphase region along the interface between the nitrile rubber and in situ PUU phases of this exemplary blend type. ; publishedVersion