| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Dascalu, Mihaela
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (9/9 displayed)
- 2023A Manganese(II) 3D Metal–Organic Framework with Siloxane-Spaced Dicarboxylic Ligand: Synthesis, Structure, and Propertiescitations
- 2023Fully carboxy-functionalized polyhedral silsesquioxanes as polar fillers to enhance the performance of dielectric silicone elastomerscitations
- 2022Soft silicone elastomers exhibiting large actuation strainscitations
- 2022Bentonite as an active natural filler for silicone leading to piezoelectric-like response materialcitations
- 2020Nanoscale Coordination Polymer of Dimanganese(II) as Infinite, Flexible Nanosheets with Photo‐Switchable Morphologycitations
- 2020Silicone elastomers filled with rare earth oxidescitations
- 2016Silicones with enhanced permittivity for dielectric elastomer actuatorscitations
- 2015Polar–nonpolar interconnected elastic networks with increased permittivity and high breakdown fields for dielectric elastomer transducerscitations
- 2015Synthesis of silicone elastomers containing trifluoropropyl groups and their use in dielectric elastomer transducerscitations
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article
A Manganese(II) 3D Metal–Organic Framework with Siloxane-Spaced Dicarboxylic Ligand: Synthesis, Structure, and Properties
Abstract
<jats:p>A new metal–organic framework {[Mn4(Cx)3(etdipy)5]·2ClO4}n (1) was prepared via the complexation of manganese ion from a Mn(ClO4)2 source with 1,3-bis(carboxypropyl)tetramethyldisiloxane (Cx) and 1,2-di(4-pyridyl)ethylene (etdipy) in the presence of 2,4-lutidine as a deprotonating agent. The single-crystal X-ray diffraction analysis revealed a dense 3D framework structure. The presence in the structure of flexible tetramethyldisiloxane moieties, which tend to orient themselves at the interface with the air, gives the compound a highly hydrophobic character, as indicated by the result of the water vapor sorption analysis in the dynamic regime, as well as the shape and stability of the water droplet on the crystalline mass of the compound. The compound is an electrical insulator, and due to its hydrophobicity, this characteristic is unaffected by environmental dampness. The thermal analysis indicated thermal stability up to about 300 °C and an unusual thermal transition for an MOF structure, more precisely a glass transition at 24 °C, the latter also being attributed to the flexible segments in the structure. The magnetic studies showed dominant antiferromagnetic interactions along the metal ion chain in compound 1.</jats:p>