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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Ruben, Mario
Karlsruhe Institute of Technology
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (13/13 displayed)
- 2024Computational demonstration of isomer- and spin-state-dependent charge transport in molecular junctions composed of charge-neutral iron(II) spin-crossover complexescitations
- 2024Unconventional Band Structure via Combined Molecular Orbital and Lattice Symmetries in a Surface‐Confined Metallated Graphdiyne Sheetcitations
- 2023A π‐Conjugated Porphyrin Complex as Cathode Material Allows Fast and Stable Energy Storage in Calcium Batteriescitations
- 2023A π‐Conjugated Porphyrin Complex as Cathode Material Allows Fast and Stable Energy Storage in Calcium Batteries
- 2023Molecular Engineering of Metalloporphyrins for High‐Performance Energy Storage: Central Metal Matterscitations
- 2022Field-Induced Single Molecule Magnetic Behavior of Mononuclear Cobalt(II) Schiff Base Complex Derived from 5-Bromo Vanillincitations
- 2021A self‐conditioned metalloporphyrin as a highly stable cathode for fast rechargeable magnesium batteries
- 2021A Self‐Conditioned Metalloporphyrin as a Highly Stable Cathode for Fast Rechargeable Magnesium Batteriescitations
- 2018Radical-lanthanide ferromagnetic interaction in a TbIII bis-phthalocyaninato complexcitations
- 2018Functionalized Graphdiyne Nanowires: On‐Surface Synthesis and Assessment of Band Structure, Flexibility, and Information Storage Potentialcitations
- 2014Meta-Positioning of Carbonitrile Functional Groups Induces Interfacial Edge-On Phase of Oligophenyl Derivativescitations
- 2013Spin-dependent electronic structure of the Co/Al(OP)3 interfacecitations
- 2011Supramolecular spin valvescitations
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article
Field-Induced Single Molecule Magnetic Behavior of Mononuclear Cobalt(II) Schiff Base Complex Derived from 5-Bromo Vanillin
Abstract
<jats:p>A mononuclear Co(II) complex of a Schiff base ligand derived from 5-Bromo-vanillin and 4-aminoantipyrine, that has a compressed tetragonal bipyramidal geometry and exhibiting field-induced slow magnetic relaxation, has been synthesized and characterized by single crystal X-ray diffraction, elemental analysis and molecular spectroscopy. In the crystal packing, a hydrogen-bonded dimer structural topology has been observed with two distinct metal centers having slightly different bond parameters. The complex has been further investigated for its magnetic nature on a SQUID magnetometer. The DC magnetic data confirm that the complex behaves as a typical S = 3/2 spin system with a sizable axial zero-field splitting parameter D/hc = 38 cm−1. The AC susceptibility data reveal that the relaxation time for the single-mode relaxation process is τ = 0.16(1) ms at T = 2.0 K and BDC = 0.12 T.</jats:p>