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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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De Rosa, Claudio
Agencia Estatal de Investigación
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (7/7 displayed)
- 2024Ring Opening Polymerization of Six- and Eight-Membered Racemic Cyclic Esters for Biodegradable Materialscitations
- 2024Ring Opening Polymerization of Six- and Eight-Membered Racemic Cyclic Esters for Biodegradable Materialscitations
- 2021Nanostructured dimethacrylate-based photopolymerizable systems by modification with diblock copolymerscitations
- 2020Tailored inclusion of semiconductor nanoparticles in nanoporous polystyrene-block-polymethyl methacrylate thin filmscitations
- 2020Semi-batch Terpolymerization of Ethylene, Propylene, and 5-Ethylidene-2-norbornene: Heterogeneous High-Ethylene EPDM Thermoplastic Elastomerscitations
- 2017Isotactic and syndiotactic alternating ethylene/propylene copolymers obtained through non-catalytic hydrogenation of highly stereoregular cis-1,4 poly(1,3-diene)scitations
- 2016Tuning ordered pattern of Pd species through controlled block copolymer self-assemblycitations
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article
Ring Opening Polymerization of Six- and Eight-Membered Racemic Cyclic Esters for Biodegradable Materials
Abstract
<jats:p>The low percentage of recyclability of the polymeric materials obtained by olefin transition metal (TM) polymerization catalysis has increased the interest in their substitution with more eco-friendly materials with reliable physical and mechanical properties. Among the variety of known biodegradable polymers, linear aliphatic polyesters produced by ring-opening polymerization (ROP) of cyclic esters occupy a prominent position. The polymer properties are highly dependent on the macromolecule microstructure, and the control of stereoselectivity is necessary for providing materials with precise and finely tuned properties. In this review, we aim to outline the main synthetic routes, the physical properties and also the applications of three commercially available biodegradable materials: Polylactic acid (PLA), Poly(Lactic-co-Glycolic Acid) (PLGA), and Poly(3-hydroxybutyrate) (P3HB), all of three easily accessible via ROP. In this framework, understanding the origin of enantioselectivity and the factors that determine it is then crucial for the development of materials with suitable thermal and mechanical properties.</jats:p>