Materials Map

Discover the materials research landscape. Find experts, partners, networks.

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The Materials Map is an open tool for improving networking and interdisciplinary exchange within materials research. It enables cross-database search for cooperation and network partners and discovering of the research landscape.

The dashboard provides detailed information about the selected scientist, e.g. publications. The dashboard can be filtered and shows the relationship to co-authors in different diagrams. In addition, a link is provided to find contact information.

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The Materials Map is still under development. In its current state, it is only based on one single data source and, thus, incomplete and contains duplicates. We are working on incorporating new open data sources like ORCID to improve the quality and the timeliness of our data. We will update Materials Map as soon as possible and kindly ask for your patience.

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in Cooperation with on an Cooperation-Score of 37%

Topics

Publications (2/2 displayed)

  • 2022Low Release Study of Cefotaxime by Functionalized Mesoporous Silica Nanomaterials5citations
  • 2022Luminescence, Paramagnetic, and Electrochemical Properties of Copper Oxides-Decorated TiO2/Graphene Oxide Nanocomposites10citations

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Vasile, Bogdan Stefan
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Cristescu, Rodica
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Istrati, Daniela
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Trușca, Roxana Doina
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Mihaiescu, Dan Eduard
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Morosan, Alina
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Baleanu, Maria
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Gaidau, Carmen
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Rosu, Marcela-Corina
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Ionita, Gabriela
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Matei, Iulia
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Virgolici, Marian
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Stanculescu, Ioana
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Bala, Daniela
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2022

Co-Authors (by relevance)

  • Vasile, Bogdan Stefan
  • Cristescu, Rodica
  • Istrati, Daniela
  • Trușca, Roxana Doina
  • Mihaiescu, Dan Eduard
  • Morosan, Alina
  • Baleanu, Maria
  • Gaidau, Carmen
  • Rosu, Marcela-Corina
  • Ionita, Gabriela
  • Matei, Iulia
  • Virgolici, Marian
  • Stanculescu, Ioana
  • Cosma, Dragos-Viorel
  • Bala, Daniela
OrganizationsLocationPeople

article

Luminescence, Paramagnetic, and Electrochemical Properties of Copper Oxides-Decorated TiO2/Graphene Oxide Nanocomposites

  • Baleanu, Maria
  • Gaidau, Carmen
  • Rosu, Marcela-Corina
  • Ionita, Gabriela
  • Matei, Iulia
  • Virgolici, Marian
  • Stanculescu, Ioana
  • Stanca, Maria
  • Cosma, Dragos-Viorel
  • Bala, Daniela
Abstract

<jats:p>The properties of newly synthesized Cu2O/CuO-decorated TiO2/graphene oxide (GO) nanocomposites (NC) were analyzed aiming to obtain insight into their photocatalytic behavior and their various applications, including water remediation, self-cleaning surfaces, antibacterial materials, and electrochemical sensors. The physico-chemical methods of research were photoluminescence (PL), electron paramagnetic resonance (EPR) spectroscopy, cyclic voltammetry (CV), and differential pulse voltammetry (DPV). The solid samples evidenced an EPR signal that can be attributed to the oxygen-vacancy defects and copper ions in correlation with PL results. Free radicals generated before and after UV-Vis irradiation of powders and aqueous dispersions of Cu2O/CuO-decorated TiO2/GO nanocomposites were studied by EPR spectroscopy using two spin traps, DMPO (5,5-dimethyl-1-pyrroline-N-oxide) and CPH (1-hydroxy-3-carboxy-2,2,5,5-tetramethylpyrrolidine), to highlight the formation of hydroxyl and superoxide reactive oxygen species, respectively. The electrochemical characterization of the NC modified carbon-paste electrodes (CPE) was carried out by CV and DPV. As such, modified carbon-paste electrodes were prepared by mixing carbon paste with copper oxides-decorated TiO2/GO nanocomposites. We have shown that GO reduces the recombination process in TiO2 by immediate electron transfer from excited TiO2 to GO sheets. The results suggest that differences in the PL, respectively, EPR data and electrochemical behavior, are due to the different copper oxides and GO content, presenting new perspectives of materials functionalization.</jats:p>

Topics
  • nanocomposite
  • dispersion
  • surface
  • photoluminescence
  • Carbon
  • Oxygen
  • reactive
  • copper
  • electron spin resonance spectroscopy
  • functionalization
  • cyclic voltammetry
  • vacancy
  • pulse voltammetry
  • cloud-point extraction