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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Gorgieva, Selestina
University of Maribor
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (7/7 displayed)
- 2023Efficiency of neat and quaternized-cellulose nanofibril fillers in chitosan membranes for direct ethanol fuel cellscitations
- 2023GO-Enabled Bacterial Cellulose Membranes by Multistep, In Situ Loading: Effect of Bacterial Strain and Loading Pattern on Nanocomposite Propertiescitations
- 2023High performance chitosan/nanocellulose-based composite membrane for alkaline direct ethanol fuel cellscitations
- 2022Efficient chitosan/nitrogen-doped reduced graphene oxide composite membranes for direct alkaline ethanol fuel cellscitations
- 2022The efficiency of chitosan-graphene oxide composite membranes modified with genipin in fuel cell applicationcitations
- 2021High oxygen barrier chitosan films neutralized by alkaline nanoparticlescitations
- 2021Efficient Chitosan/Nitrogen-doped Reduced Graphene Oxide Composite Membranes for Direct Alkaline Ethanol Fuel Cellscitations
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article
Efficient Chitosan/Nitrogen-doped Reduced Graphene Oxide Composite Membranes for Direct Alkaline Ethanol Fuel Cells
Abstract
<p>Herein, we prepared a series of nanocomposite membranes based on chitosan (CS) and three compositionally and structurally different N-doped graphene derivatives. Two-dimensional (2D) and quasi 1D N-doped reduced graphene oxides (N-rGO) and nanoribbons (N-rGONRs), as well as 3D porous N-doped graphitic polyenaminone particles (N-pEAO), were synthesized and characterized fully to confirm their graphitic structure, morphology, and nitrogen (pyridinic, pyrrolic, and quaternary or graphitic) group contents. The largest (0.07%) loading of N-doped graphene derivatives impacted the morphology of the CS membrane significantly, reducing the crystallinity, tensile properties, and the KOH uptake, and increasing (by almost 10-fold) the ethanol permeability. Within direct alkaline ethanol test cells, it was found that CS/N rGONRs (0.07 %) membrane (Pmax. = 3.7 mWcm<sup>−2</sup>) outperformed the pristine CS membrane significantly (Pmax. = 2.2 mWcm<sup>−2</sup>), suggesting the potential of the newly proposed membranes for application in direct ethanol fuel cells.</p>