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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Benyoucef, Abdelghani
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (18/18 displayed)
- 2022Development and Characterization of Novel Hybrid Materials Formed from ZnO-SiO2-Modified and Polyaniline for Organic Dyes Adsorption and Electrochemical Supercapacitor Applications
- 2022Application of Activated Carbon Adsorbents Prepared from Prickly Pear Fruit Seeds and a Conductive Polymer Matrix to Remove Congo Red from Aqueous Solutionscitations
- 2022Effects of Incorporating Titanium Dioxide with Titanium Carbide on Hybrid Materials Reinforced with Polyaniline: Synthesis, Characterization, Electrochemical and Supercapacitive Propertiescitations
- 2022Hydrogels obtained from aniline and piperazine: Synthesis, characterization and their application in hybrid supercapacitorscitations
- 2021Development, Investigation, and Comparative Study of the Effects of Various Metal Oxides on Optical Electrochemical Properties Using a Doped PANI Matrixcitations
- 2021Synthesis of PANI@ZnO Hybrid Material and Evaluations in Adsorption of Congo Red and Methylene Blue Dyes: Structural Characterization and Adsorption Performance
- 2021Synthesis and characterization of polymer/V2O5 composites based on poly(2‐aminodiphenylamine)citations
- 2020Reactive Insertion of PEDOT-PSS in SWCNT@Silica Composites and its Electrochemical Performancecitations
- 2019Preparation of polypyrrole (PPy)-derived polymer/ZrO2 nanocompositescitations
- 2019New poly(o-phenylenediamine)/modified-clay nanocomposites: A study on spectral, thermal, morphological and electrochemical characteristicscitations
- 2019Tailoring the properties of polyanilines/SiC nanocomposites by engineering monomer and chain substituentscitations
- 2017A novel conducting nanocomposite obtained by p-anisidine and aniline with titanium(IV) oxide nanoparticles: Synthesis, Characterization, and Electrochemical propertiescitations
- 2016PANI-derived polymer/Al2O3 nanocomposites: synthesis, characterization, and electrochemical studiescitations
- 2015Characterization and electrochemical properties of conducting nanocomposites synthesized from p-anisidine and aniline with titanium carbide by chemical oxidative methodcitations
- 2014Synthesis, characterization and conducting properties of nanocomposites of intercalated 2-aminophenol with aniline in codium-montmorillonitecitations
- 2014Synthesis, Characterization and Conducting Properties of Nanocomposites of Intercalated 2-Aminophenol with Aniline in Sodium-Montmorillonitecitations
- 2013Effect of the intercalated cation-exchanged on the properties of nanocomposites prepared by 2-aminobenzene sulfonic acid with aniline and montmorillonitecitations
- 2007Voltammetric and in situ FTIRS study of the electropolymerization of o-aminobenzoic acid at gold and graphite carbon electrodes: influence of pH on the electrochemical behaviour of polymer filmscitations
Places of action
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article
Application of Activated Carbon Adsorbents Prepared from Prickly Pear Fruit Seeds and a Conductive Polymer Matrix to Remove Congo Red from Aqueous Solutions
Abstract
<jats:p>The present work was aimed to evaluate the adsorption properties of activated carbons based on prickly pear seeds (PPS) and conductive polymer matrix based on polyaniline (PANI) for the removal of anionic Congo red (CR) dye from aqueous solutions. The adsorbent was prepared by polymerization of aniline in the presence of activated PPS by phosphoric acid and sodium hydroxide. The samples were characterized using X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), Fourier-transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA) and the Brunauer–Emmett–Teller (BET) methods. The adsorption kinetics were studied using UV-visible (UV/Vis) spectroscopy. The characterization data suggest that the adsorption of the Congo red dye is enhanced because PANI chain molecules, which are especially accountable for removal through π–π interaction and H–bonding with the CR, are adsorbed/tethered onto the acid-activated PPS (PPSH), and thus surmount the mass transfer limitation by being best exposed to the CR-adsorbed molecule. The adsorption kinetics follows the pseudo-second order process. The correlation coefficients (R2) for Langmuir, Freundlich and Tempkin showed that the adsorption values obey Freundlich and Tempkin isotherm models. Moreover, the isotherm was most accurately described by the Freundlich model, and the maximum removal percentage was calculated to be 91.14% under optimized conditions of pH 6.6, 1 g/L of adsorbent dosage, and an initial CR dye concentration of 20 mg·L−1. Importantly, the hybrid adsorbent exhibited the highest adsorption capacity (80.15%) after five cycles of the adsorption–desorption process. Thermodynamic parameters, such as entropy changes, enthalpy changes and Gibbs free energy, were also evaluated. These results indicated that the PANI matrix can generally be better utilized for the removal of Congo red dye when appropriately dispersed on the surface of suitable support materials. These results provide a new direction to promote the separable adsorbents with increasing performance for adsorption of dye impurities from wastewater.</jats:p>