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| Naji, M. |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Kočí, Jan | Prague |
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| Azam, Siraj |
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| Ali, M. A. |
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| Rančić, M. |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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Alifah, Miratul
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Publications (3/3 displayed)
- 2023Oxide Strontium-Barium Perovskites Ceramics: Examinations of Structural Phase Transitions and Potential Application as Oxygen Carriers
- 2022Thermal, Microstructural and Electrochemical Hydriding Performance of a Mg65Ni20Cu5Y10 Metallic Glass Catalyzed by CNT and Processed by High-Pressure Torsioncitations
- 2015The Effect of KOH Activation in Synthesis and Characterization of Zeolitic Imidazolate Frameworks-8 (ZIF-8) Templated Mesoporous Carboncitations
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article
Thermal, Microstructural and Electrochemical Hydriding Performance of a Mg65Ni20Cu5Y10 Metallic Glass Catalyzed by CNT and Processed by High-Pressure Torsion
Abstract
<jats:p>A Mg65Ni20Cu5Y10 metallic glass was produced by melt spinning and was mixed with a 5 wt.% multiwall carbon nanotube additive in a high-energy ball mill. Subsequently, the composite mixture was exposed to high-pressure torsion deformation with different torsion numbers. Complimentary XRD and DSC experiments confirmed the exceptional structural and thermal stability of the amorphous phase against severe plastic deformation. Combined high-resolution transmission electron microscopy observations and fast Fourier transform analysis revealed deformation-induced Mg2Ni nanocrystals, together with the structural and morphological stability of the nanotubes. The electrochemical hydrogen discharge capacity of the severely deformed pure metallic glass was substantially lower than that of samples with the nanotube additive for several cycles. It was also established that the most deformed sample containing nanotubes exhibited a drastic breakdown in the electrochemical capacity after eight cycles.</jats:p>